3-O-benzoyl-1,2-isopropylidene-α-D-ribo-pentodialdo-1,4-furanose

Base Information

• Chemical Name: 3-O-benzoyl-1,2-isopropylidene-α-D-ribo-pentodialdo-1,4-furanose
• CAS No.: 1039343-60-6
• Molecular Formula: C₁₅H₁₆O₆
• Molecular Weight: 292.288
• Mol file: 1039343-60-6.mol

Synonyms:3-O-benzoyl-1,2-isopropylidene-α-D-ribo-pentodialdo-1,4-furanose

Chemical Property of 3-O-benzoyl-1,2-isopropylidene-α-D-ribo-pentodialdo-1,4-furanose

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 3-O-benzoyl-1,2-isopropylidene-α-D-ribo-pentodialdo-1,4-furanose

There total 4 articles about 3-O-benzoyl-1,2-isopropylidene-α-D-ribo-pentodialdo-1,4-furanose which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

(+)-3-deoxy-1,2:5,6-di-O-isopropylidene-α-D-allofuranos-3-yl benzoate (29474-73-5) → 3-O-benzoyl-1,2-isopropylidene-α-D-ribo-pentodialdo-1,4-furanose (1039343-60-6)

Guidance literature:

With periodic acid; In ethyl acetate; for 2h; Ambient temperature;

DOI:10.1021/jm980163m

Reference yield:

3-O-benzoyl-1,2-O-isopropylidene-α-D-allofuranose (31795-13-8) → 3-O-benzoyl-1,2-isopropylidene-α-D-ribo-pentodialdo-1,4-furanose (1039343-60-6)

Guidance literature:

With sodium periodate; In water; acetone; at 20 ℃; for 8h;

DOI:10.1016/j.tet.2006.07.056

Reference yield:

benzoyl cyanide (613-90-1) → 3-O-benzoyl-1,2-isopropylidene-α-D-ribo-pentodialdo-1,4-furanose (1039343-60-6)

Guidance literature:

Multi-step reaction with 2 steps

1: Et₃N / acetonitrile / 15 h / 20 °C

2: NaIO₄ / acetone; H₂O / 0 °C

With sodium periodate; triethylamine; In water; acetone; acetonitrile;

DOI:10.1016/j.tet.2006.03.008

upstream raw materials:

(+)-3-deoxy-1,2:5,6-di-O-isopropylidene-α-D-allofuranos-3-yl benzoate

3-O-benzoyl-1,2-O-isopropylidene-α-D-allofuranose

benzoyl cyanide

Diacetone D-glucose

Downstream raw materials:

3-O-benzoyl-6,6-dibromo-5,6-dideoxy-1,2-O-isopropylidene-D-allofuranose

(E)-3-O-benzoyl-5,6-dideoxy-6-fluoro-1,2-isopropylidene-6-phenylsulfonyl-α-D-ribo-hex-5-enofuranose

ethyl 3-O-benzoyl-5,6,7,8-tetradeoxy-1,2-O-isopropylidene-α-D-ribo-non-5(Z)-enofuranuronate

(E)-3-O-benzoyl-5,6-dideoxy-1,2-isopropylidene-6-phenylsulfonyl-α-D-ribo-hex-5-enofuranose