[platinum(II)(4'-p-tolylterpyridine)(phenylacetylide)] perchlorate

Base Information

• Chemical Name: [platinum(II)(4'-p-tolylterpyridine)(phenylacetylide)] perchlorate
• CAS No.: 475470-43-0
• Molecular Formula: C₃₀H₂₂N₃Pt*ClO₄
• Molecular Weight: 719.055
• Mol file: 475470-43-0.mol

Synonyms:[platinum(II)(4'-p-tolylterpyridine)(phenylacetylide)] perchlorate

Chemical Property of [platinum(II)(4'-p-tolylterpyridine)(phenylacetylide)] perchlorate

Chemical Property:

Purity/Quality:

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MSDS Files:

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Technology Process of [platinum(II)(4'-p-tolylterpyridine)(phenylacetylide)] perchlorate

There total 2 articles about [platinum(II)(4'-p-tolylterpyridine)(phenylacetylide)] perchlorate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 76.0%

chloro[4'-(4-methylphenyl)-2,2':6',2''-terpyridine]platinum(II) chloride (727721-37-1) + phenylacetylide anion (20404-08-4) + sodium perchlorate → [platinum(II)(4'-p-tolylterpyridine)(phenylacetylide)] perchlorate (475470-43-0)

Guidance literature:

With triethylamine; copper(l) iodide; In N,N-dimethyl-formamide; 2 equiv amounts of acetylide in DMF in the presence of catalyst CuI and triethyl amine at room temp., metathesis with NaClO4; recrystd. by vapor diffusion of diethyl ether into an acetonitrile soln.;

DOI:10.1021/ic025580a

Reference yield:

[platinum(II)(4'-p-tolylterpyridine)(phenylacetylide)] chloride (856412-44-7) + potassium perchlorate → [platinum(II)(4'-p-tolylterpyridine)(phenylacetylide)] perchlorate (475470-43-0)

Guidance literature:

In not given; chloride Pt complex exchanged with KClO4;

DOI:10.1021/jp072187n

upstream raw materials:

chloro[4'-(4-methylphenyl)-2,2':6',2''-terpyridine]platinum(II) chloride

phenylacetylide anion

[platinum(II)(4'-p-tolylterpyridine)(phenylacetylide)] chloride