[platinum(II)(4'-p-tolylterpyridine)(phenylacetylide)] chloride

Base Information

• Chemical Name: [platinum(II)(4'-p-tolylterpyridine)(phenylacetylide)] chloride
• CAS No.: 856412-44-7
• Molecular Formula: C₃₀H₂₂N₃Pt*Cl
• Molecular Weight: 655.058
• Mol file: 856412-44-7.mol

Synonyms:[platinum(II)(4'-p-tolylterpyridine)(phenylacetylide)] chloride

Chemical Property of [platinum(II)(4'-p-tolylterpyridine)(phenylacetylide)] chloride

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [platinum(II)(4'-p-tolylterpyridine)(phenylacetylide)] chloride

There total 6 articles about [platinum(II)(4'-p-tolylterpyridine)(phenylacetylide)] chloride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 65.0%

chloro[4'-(4-methylphenyl)-2,2':6',2''-terpyridine]platinum(II) chloride (727721-37-1) + phenylacetylene (536-74-3) → [platinum(II)(4'-p-tolylterpyridine)(phenylacetylide)] chloride (856412-44-7)

Guidance literature:

phenylacetylene; With potassium hydroxide; In methanol; at 20 ℃; for 0.75h;

chloro[4'-(4-methylphenyl)-2,2':6',2''-terpyridine]platinum(II) chloride; With copper(l) iodide; In methanol; at 20 ℃; for 12h;

DOI:10.1002/chem.201800856

Reference yield:

3,5-difluorobenzaldehyde (32085-88-4) → [platinum(II)(4'-p-tolylterpyridine)(phenylacetylide)] chloride (856412-44-7)

Guidance literature:

Multi-step reaction with 3 steps

1.1: sodium hydroxide; ammonium hydroxide / ethanol / 24 h / 35 °C

2.1: methanol / 12 h / Reflux; Inert atmosphere

3.1: potassium hydroxide / methanol / 0.75 h / 20 °C

3.2: 12 h / 20 °C

With ammonium hydroxide; potassium hydroxide; sodium hydroxide; In methanol; ethanol;

DOI:10.1002/chem.201800856

Reference yield:

4'-(4-methylphenyl)-2,2':6',2-terpyridine (89972-77-0) → [platinum(II)(4'-p-tolylterpyridine)(phenylacetylide)] chloride (856412-44-7)

Guidance literature:

Multi-step reaction with 2 steps

1.1: methanol / 12 h / Reflux; Inert atmosphere

2.1: potassium hydroxide / methanol / 0.75 h / 20 °C

2.2: 12 h / 20 °C

With potassium hydroxide; In methanol;

DOI:10.1002/chem.201800856

upstream raw materials:

chloro[4'-(4-methylphenyl)-2,2':6',2''-terpyridine]platinum(II) chloride

phenylacetylene

3,5-difluorobenzaldehyde

2,2':6,2''-terpyridine

Downstream raw materials:

[platinum(II)(4'-p-tolylterpyridine)(phenylacetylide)] perchlorate