1-[(3S)-3-(4-chlorophenyl)cyclobut-1-enyloxyl]-1,1-diethyl-1-silapropane

Base Information

Chemical Name:1-[(3S)-3-(4-chlorophenyl)cyclobut-1-enyloxyl]-1,1-diethyl-1-silapropane
CAS No.:245662-60-6
Molecular Formula:C₁₆H₂₃ClOSi
Molecular Weight:294.897
Hs Code.:

Synonyms:1-[(3S)-3-(4-chlorophenyl)cyclobut-1-enyloxyl]-1,1-diethyl-1-silapropane

Suppliers and Price of 1-[(3S)-3-(4-chlorophenyl)cyclobut-1-enyloxyl]-1,1-diethyl-1-silapropane

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of 1-[(3S)-3-(4-chlorophenyl)cyclobut-1-enyloxyl]-1,1-diethyl-1-silapropane

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Technology Process of 1-[(3S)-3-(4-chlorophenyl)cyclobut-1-enyloxyl]-1,1-diethyl-1-silapropane

There total 3 articles about 1-[(3S)-3-(4-chlorophenyl)cyclobut-1-enyloxyl]-1,1-diethyl-1-silapropane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 70.0%

: 994-30-9
triethylsilyl chloride

: 152714-07-3
3-(4-chlorophenyl)cyclobutanone

: 245662-60-6
1-[(3S)-3-(4-chlorophenyl)cyclobut-1-enyloxyl]-1,1-diethyl-1-silapropane

Guidance literature:: With lithium (S,S)-bis(α-methylbenzyl)amide; In tetrahydrofuran; hexane; at -100 ℃; for 0.166667h;
DOI:10.1016/S0957-4166(99)00235-9

Reference yield:

: 1073-67-2,24991-47-7
4-vinylbenzyl chloride

: 245662-60-6
1-[(3S)-3-(4-chlorophenyl)cyclobut-1-enyloxyl]-1,1-diethyl-1-silapropane

Guidance literature:: Multi-step reaction with 3 steps

1: 91 percent / Zn-Cu; POCl₃ / diethyl ether / 20 h / 20 °C

2: 93 percent / Zn; AcOH / 14 h / 20 °C

3: 70 percent / lithium (S,S')-α,α'-dimethylbenzamide / tetrahydrofuran; hexane / 0.17 h / -100 °C

With copper; lithium (S,S)-bis(α-methylbenzyl)amide; acetic acid; zinc; trichlorophosphate; In tetrahydrofuran; diethyl ether; hexane;
DOI:10.1016/S0957-4166(99)00235-9

Reference yield:

: 191019-76-8
2,2-dichloro-3-(4'-chlorophenyl)cyclobutanone

: 245662-60-6
1-[(3S)-3-(4-chlorophenyl)cyclobut-1-enyloxyl]-1,1-diethyl-1-silapropane

Guidance literature:: Multi-step reaction with 2 steps

1: 93 percent / Zn; AcOH / 14 h / 20 °C

2: 70 percent / lithium (S,S')-α,α'-dimethylbenzamide / tetrahydrofuran; hexane / 0.17 h / -100 °C

With lithium (S,S)-bis(α-methylbenzyl)amide; acetic acid; zinc; In tetrahydrofuran; hexane;
DOI:10.1016/S0957-4166(99)00235-9