tetrakis(tert-butyl isocyanide)copper(I) hexafluorophosphate

Base Information

• Chemical Name: tetrakis(tert-butyl isocyanide)copper(I) hexafluorophosphate
• CAS No.: 99536-60-4
• Molecular Formula: C₂₀H₃₆CuN₄*F₆P
• Molecular Weight: 541.043
• Mol file: 99536-60-4.mol

Synonyms:tetrakis(tert-butyl isocyanide)copper(I) hexafluorophosphate

Chemical Property of tetrakis(tert-butyl isocyanide)copper(I) hexafluorophosphate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of tetrakis(tert-butyl isocyanide)copper(I) hexafluorophosphate

There total 2 articles about tetrakis(tert-butyl isocyanide)copper(I) hexafluorophosphate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

tetrakis(actonitrile)copper(I) hexafluorophosphate (64443-05-6) + N,N'-1,2-ethylenebis(pyridin-2-thione) (161989-69-1) → ((C5H5)2WH2)2Cu(1+)*PF6(1-) = {((C5H5)2WH2)2Cu}PF6 + ((C5H5)2MoH2)2Cu(1+)*PF6(1-) = {((C5H5)2MoH2)2Cu}PF6 + tetrakis(xylyl isocyanide)copper(I) hexafluorophosphate (99935-11-2) + Cu6Re4H24(2+)*8P(C6H5)3*2PF6(1-) = {Cu6(ReH6(P(C6H5)3)2)4}(PF6)2 + tetrakis(tert-butyl isocyanide)copper(I) hexafluorophosphate (99536-60-4)

Guidance literature:

In dichloromethane; under Ar; to soln. of Cu-complex in CH2Cl2 was added dropwise soln. of ligand in CH2Cl2; soln. stirred for 1 h;

DOI:10.1002/(SICI)1099-0682(200002)2000:2<393::AID-EJIC393>3.0.CO;2-2

Reference yield:

tetrakis(actonitrile)copper(I) hexafluorophosphate (64443-05-6) + N,N'-1,2-ethylenebis(pyridin-2-thione) (161989-69-1) → ((C5H5)2WH2)2Cu(1+)*PF6(1-) = {((C5H5)2WH2)2Cu}PF6 + ((C5H5)2MoH2)2Cu(1+)*PF6(1-) = {((C5H5)2MoH2)2Cu}PF6 + tetrakis(xylyl isocyanide)copper(I) hexafluorophosphate (99935-11-2) + Cu6Re4H24(2+)*8P(C6H5)3*2PF6(1-) = {Cu6(ReH6(P(C6H5)3)2)4}(PF6)2 + tetrakis(tert-butyl isocyanide)copper(I) hexafluorophosphate (99536-60-4) + ([Cu2(N,N'-ethylenebis(pyridin-2-thione)3)](PF6)2)n

Guidance literature:

In dichloromethane; under Ar; to soln. of Cu-complex in CH2Cl2 was added dropwise soln. of ligand in CH2Cl2; soln. stirred for 1 h;

DOI:10.1002/(SICI)1099-0682(200002)2000:2<393::AID-EJIC393>3.0.CO;2-2

Reference yield: 75.0%

tetrakis(tert-butyl isocyanide)copper(I) hexafluorophosphate (99536-60-4) → bis(tert-butyl isocyanide)(1,2-bis(diphenylphosphino)ethane)copper(I) hexafluorophosphate (99536-70-6)

Guidance literature:

With potassium hexafluorophosphate; In ethanol; refluxing in ethanol for 48 h (N2 atm.);; recrystd. from acetone-toluene (1:2);;

DOI:10.1016/S0020-1693(00)86767-5

upstream raw materials:

tetrakis(actonitrile)copper(I) hexafluorophosphate

N,N'-1,2-ethylenebis(pyridin-2-thione)

Downstream raw materials:

bis(tert-butyl isocyanide)(1,2-bis(diphenylphosphino)ethane)copper(I) hexafluorophosphate