methyl(r-2-phenyl-c-4-(3',4'-methylenedioxyphenyl)-1,3-dioxan-c-5-yl)-acetate

Base Information

Chemical Name:methyl(r-2-phenyl-c-4-(3',4'-methylenedioxyphenyl)-1,3-dioxan-c-5-yl)-acetate
CAS No.:108763-74-2
Molecular Formula:C₂₀H₂₀O₆
Molecular Weight:356.375
Hs Code.:

Synonyms:methyl(r-2-phenyl-c-4-(3',4'-methylenedioxyphenyl)-1,3-dioxan-c-5-yl)-acetate

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of methyl(r-2-phenyl-c-4-(3',4'-methylenedioxyphenyl)-1,3-dioxan-c-5-yl)-acetate

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Technology Process of methyl(r-2-phenyl-c-4-(3',4'-methylenedioxyphenyl)-1,3-dioxan-c-5-yl)-acetate

There total 7 articles about methyl(r-2-phenyl-c-4-(3',4'-methylenedioxyphenyl)-1,3-dioxan-c-5-yl)-acetate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

: 186581-53-3,908094-01-9,334-88-3
diazomethane

: 108763-73-1
((2S,4R,5R)-4-Benzo[1,3]dioxol-5-yl-2-phenyl-[1,3]dioxan-5-yl)-acetic acid

: 108763-74-2
methyl(r-2-phenyl-c-4-(3',4'-methylenedioxyphenyl)-1,3-dioxan-c-5-yl)-acetate

Guidance literature:: In diethyl ether; at 0 ℃;
DOI:10.1016/S0040-4020(01)87655-9

Reference yield:

: 120-57-0,30024-74-9
piperonal

: 108763-74-2
methyl(r-2-phenyl-c-4-(3',4'-methylenedioxyphenyl)-1,3-dioxan-c-5-yl)-acetate

Guidance literature:: Multi-step reaction with 6 steps

1: 1.) (i.Pr)2NH, n.BuLi / 1.) THF/hexane, -78 deg C, 45 min, 2.) THF/hexane, -78 deg C, 30 min

2: 95 percent / LiAlH₄ / tetrahydrofuran / 2 h / 0 °C

3: 70 percent / CuSO₄ / CHCl₃ / 48 h / Ambient temperature

4: 86 percent / CrO_3.Py₂ / CH₂Cl₂ / 0.25 h

5: 78 percent / Ag₂O, NaOH / H₂O; methanol / 4 h / 60 °C

6: 100 percent / diethyl ether / 0 °C

With sodium hydroxide; lithium aluminium tetrahydride; n-butyllithium; dipyridine chromium trioxide; copper(II) sulfate; diisopropylamine; silver(l) oxide; In tetrahydrofuran; methanol; diethyl ether; dichloromethane; chloroform; water;
DOI:10.1016/S0040-4020(01)87655-9

Reference yield:

: 100-52-7
benzaldehyde

: 108763-74-2
methyl(r-2-phenyl-c-4-(3',4'-methylenedioxyphenyl)-1,3-dioxan-c-5-yl)-acetate

Guidance literature:: Multi-step reaction with 4 steps

1: 70 percent / CuSO₄ / CHCl₃ / 48 h / Ambient temperature

2: 86 percent / CrO_3.Py₂ / CH₂Cl₂ / 0.25 h

3: 78 percent / Ag₂O, NaOH / H₂O; methanol / 4 h / 60 °C

4: 100 percent / diethyl ether / 0 °C

With sodium hydroxide; dipyridine chromium trioxide; copper(II) sulfate; silver(l) oxide; In methanol; diethyl ether; dichloromethane; chloroform; water;
DOI:10.1016/S0040-4020(01)87655-9