KCN-Triox₂

Base Information

• Chemical Name: KCN-Triox₂
• CAS No.: 1313274-96-2
• Molecular Formula: C₃₉H₄₈O₁₃Si
• Molecular Weight: 752.888
• Mol file: 1313274-96-2.mol

Synonyms:KCN-Triox₂

Chemical Property of KCN-Triox₂

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

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Technology Process of KCN-Triox₂

There total 35 articles about KCN-Triox₂ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 88.0%

KCN-Triox1 (1313274-97-3) → KCN-Triox2 (1313274-96-2)

Guidance literature:

With triethylamine tris(hydrogen fluoride); In acetonitrile; for 0.25h; Inert atmosphere;

DOI:10.1002/anie.201410369

Reference yield: 36.0%

C47H64O13Si2 → C39H48O13Si (1313275-28-3) + KCN-Triox2 (1313274-96-2)

Guidance literature:

C₄₇H₆₄O₁₃Si₂; With triethylamine trihydrochloride; In acetonitrile; at 23 ℃; for 0.25h;

In dichloromethane; pH=7; Aqueous phosphate buffer;

Reference yield: 34.0%

(S)-1-diazo-3-epoxy-5,5-dimethoxypenta-2,4-dione (1313275-02-3) + C39H54O8Si2 (1313275-00-1) → C39H48O13Si (1313275-28-3) + KCN-Triox2 (1313274-96-2)

Guidance literature:

(S)-1-diazo-3-epoxy-5,5-dimethoxypenta-2,4-dione; C₃₉H₅₄O₈Si₂; With dirhodium tetraacetate; In dichloromethane; at 23 ℃; for 2h; Molecular sieve;

With triethylamine tris(hydrogen fluoride); at 23 ℃; for 0.25h;

DOI:10.1073/pnas.1015257108

upstream raw materials:

6-(tert-butyl-dimethyl-silanyloxy)-4-(4-methoxy-benzyloxy)-cyclohex-2-enone

(2R,3S)-4-tert-butyldimethylsilyloxy-1-diazo-3-epoxy-5,5-dimethoxypenta-2-one

(2R,3S)-diazo-3-epoxy-4-hydroxy-5,5-dimethoxypenta-2-one

(S)-1-diazo-3-epoxy-5,5-dimethoxypenta-2,4-dione

Downstream raw materials:

C₄₉H₆₂O₁₈Si