(2S,5R)-2-Methyl-3-phenylsulfanylmethyl-5-((E)-styryl)-2,5-dihydro-furan

Base Information

Chemical Name:(2S,5R)-2-Methyl-3-phenylsulfanylmethyl-5-((E)-styryl)-2,5-dihydro-furan
CAS No.:137845-30-8
Molecular Formula:C₂₀H₂₀OS
Molecular Weight:308.444
Hs Code.:

Synonyms:(2S,5R)-2-Methyl-3-phenylsulfanylmethyl-5-((E)-styryl)-2,5-dihydro-furan

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of (2S,5R)-2-Methyl-3-phenylsulfanylmethyl-5-((E)-styryl)-2,5-dihydro-furan

Chemical Property:

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Technology Process of (2S,5R)-2-Methyl-3-phenylsulfanylmethyl-5-((E)-styryl)-2,5-dihydro-furan

There total 5 articles about (2S,5R)-2-Methyl-3-phenylsulfanylmethyl-5-((E)-styryl)-2,5-dihydro-furan which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 14371-10-9
(E)-3-phenylpropenal

: 137845-09-1
Acetic acid (Z)-1-methyl-3-phenylsulfanyl-2-trimethylsilanylmethyl-allyl ester

: 137845-30-8
(2S,5R)-2-Methyl-3-phenylsulfanylmethyl-5-((E)-styryl)-2,5-dihydro-furan

Guidance literature:: With palladium diacetate; trimethylsilyl acetate; 2,4-bis<(4,6-dimethyl-1,3,2-dioxaphosphorinan-2-yl)oxy>pentane; In 1,4-dioxane; at 100 ℃;
DOI:10.1021/ja00023a094

Reference yield:

: 89005-19-6
3-(phenylsulfanyl)propargyl alcohol

: 137845-30-8
(2S,5R)-2-Methyl-3-phenylsulfanylmethyl-5-((E)-styryl)-2,5-dihydro-furan

Guidance literature:: Multi-step reaction with 5 steps

1: 81 percent / s-C₄H₉MgCl, CuCl / diethyl ether

2: 67 percent / PCC-celite / CH₂Cl₂ / 0 °C

3: tetrahydrofuran / 0 °C

4: C₅H₅N / CH₂Cl₂ / 0 °C

5: Pd(OAc)2, 2,4-bis<(4,6-dimethyl-1,3,2-dioxaphosphorinan-2-yl)oxy>pentane, (CH₃)3SnOAc / dioxane / 100 °C

With pyridine; palladium diacetate; trimethylsilyl acetate; 2,4-bis<(4,6-dimethyl-1,3,2-dioxaphosphorinan-2-yl)oxy>pentane; pyridinium chlorochromate on silica gel; s-butylmagnesium chloride; copper(l) chloride; In tetrahydrofuran; 1,4-dioxane; diethyl ether; dichloromethane;
DOI:10.1021/ja00023a094

Reference yield:

: 137845-36-4
(Z)-3-Phenylsulfanyl-2-trimethylsilanylmethyl-propenal

: 137845-30-8
(2S,5R)-2-Methyl-3-phenylsulfanylmethyl-5-((E)-styryl)-2,5-dihydro-furan

Guidance literature:: Multi-step reaction with 3 steps

1: tetrahydrofuran / 0 °C

2: C₅H₅N / CH₂Cl₂ / 0 °C

3: Pd(OAc)2, 2,4-bis<(4,6-dimethyl-1,3,2-dioxaphosphorinan-2-yl)oxy>pentane, (CH₃)3SnOAc / dioxane / 100 °C

With pyridine; palladium diacetate; trimethylsilyl acetate; 2,4-bis<(4,6-dimethyl-1,3,2-dioxaphosphorinan-2-yl)oxy>pentane; In tetrahydrofuran; 1,4-dioxane; dichloromethane;
DOI:10.1021/ja00023a094