benzyl-O-[3-O-benzyl-4-methylamino-2,4-dideoxy-β-L-xylopyranosyl]-(1->6)-2,3-di-O-benzyl-4-O-methyl-β-D-glucopyranoside

Base Information

Chemical Name:benzyl-O-[3-O-benzyl-4-methylamino-2,4-dideoxy-β-L-xylopyranosyl]-(1->6)-2,3-di-O-benzyl-4-O-methyl-β-D-glucopyranoside
CAS No.:309758-13-2
Molecular Formula:C₄₁H₄₉NO₈
Molecular Weight:683.842
Hs Code.:

Synonyms:benzyl-O-[3-O-benzyl-4-methylamino-2,4-dideoxy-β-L-xylopyranosyl]-(1->6)-2,3-di-O-benzyl-4-O-methyl-β-D-glucopyranoside

Suppliers and Price of benzyl-O-[3-O-benzyl-4-methylamino-2,4-dideoxy-β-L-xylopyranosyl]-(1->6)-2,3-di-O-benzyl-4-O-methyl-β-D-glucopyranoside

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of benzyl-O-[3-O-benzyl-4-methylamino-2,4-dideoxy-β-L-xylopyranosyl]-(1->6)-2,3-di-O-benzyl-4-O-methyl-β-D-glucopyranoside

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of benzyl-O-[3-O-benzyl-4-methylamino-2,4-dideoxy-β-L-xylopyranosyl]-(1->6)-2,3-di-O-benzyl-4-O-methyl-β-D-glucopyranoside

There total 9 articles about benzyl-O-[3-O-benzyl-4-methylamino-2,4-dideoxy-β-L-xylopyranosyl]-(1->6)-2,3-di-O-benzyl-4-O-methyl-β-D-glucopyranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 35.0%

: 63629-66-3
4-O-methyl-1,2,3-O-benzyl-β-D-glucopyranoside

: 309758-12-1
((3S,4S)-4-Benzyloxy-6-fluoro-tetrahydro-pyran-3-yl)-carbamic acid tert-butyl ester

: 309758-13-2
benzyl-O-[3-O-benzyl-4-methylamino-2,4-dideoxy-β-L-xylopyranosyl]-(1->6)-2,3-di-O-benzyl-4-O-methyl-β-D-glucopyranoside

: benzyl-O-[3-O-benzyl-4-methylamino-2,4-dideoxy-α-L-xylopyranosyl]-(1->6)-2,3-di-O-benzyl-4-O-methyl-β-D-glucopyranoside

Guidance literature:: 4-O-methyl-1,2,3-O-benzyl-β-D-glucopyranoside; ((3S,4S)-4-Benzyloxy-6-fluoro-tetrahydro-pyran-3-yl)-carbamic acid tert-butyl ester; With silver perchlorate; tin(ll) chloride; In tetrahydrofuran; at -78 - -15 ℃; for 6h;

With lithium aluminium tetrahydride; In tetrahydrofuran; for 1h; Further stages.; Heating;
DOI:10.1021/jo000911r

Reference yield:

: 100-39-0
benzyl bromide

: 309758-13-2
benzyl-O-[3-O-benzyl-4-methylamino-2,4-dideoxy-β-L-xylopyranosyl]-(1->6)-2,3-di-O-benzyl-4-O-methyl-β-D-glucopyranoside

Guidance literature:: Multi-step reaction with 6 steps

1.1: 80 percent / NaH / dimethylformamide / 1.5 h

2.1: OsO₄; NMO / acetone; 2-methyl-propan-2-ol / 2 h

3.1: 1.22 g / tetrahydrofuran; H₂O / 1 h

4.1: 81 percent / TsOH*H₂O / dioxane; H₂O / 21 h / 20 °C

5.1: 89 percent / DAST; 4A MS / tetrahydrofuran / 20 h / -78 °C

6.1: AgClO₄; SnCl₂; 4A MS / tetrahydrofuran / 6 h / -78 - -15 °C

6.2: 35 percent / LiAlH₄ / tetrahydrofuran / 1 h / Heating

With osmium(VIII) oxide; N-methyl-2-indolinone; silver perchlorate; sodium hydride; toluene-4-sulfonic acid; 4,4'-diaminostilbene-2,2'-disulfonic acid; tin(ll) chloride; In tetrahydrofuran; 1,4-dioxane; water; N,N-dimethyl-formamide; acetone; tert-butyl alcohol; 1.1: Alkylation / 2.1: dihydroxylation / 3.1: Oxidation / 4.1: Hydrolysis / 5.1: Substitution / 6.1: glycosulation / 6.2: Reduction;
DOI:10.1021/jo000911r

Reference yield:

: 95712-24-6
benzyl 6-O-(4-methoxybenzyl)-2,3-di-O-benzyl-β-D-glucopyranoside

: 309758-13-2
benzyl-O-[3-O-benzyl-4-methylamino-2,4-dideoxy-β-L-xylopyranosyl]-(1->6)-2,3-di-O-benzyl-4-O-methyl-β-D-glucopyranoside

Guidance literature:: Multi-step reaction with 3 steps

1.1: NaH / tetrahydrofuran / 1.5 h

2.1: 63 percent / DDQ / CH₂Cl₂; H₂O / 5 h

3.1: AgClO₄; SnCl₂; 4A MS / tetrahydrofuran / 6 h / -78 - -15 °C

3.2: 35 percent / LiAlH₄ / tetrahydrofuran / 1 h / Heating

With silver perchlorate; sodium hydride; 2,3-dicyano-5,6-dichloro-p-benzoquinone; tin(ll) chloride; In tetrahydrofuran; dichloromethane; water; 1.1: Methylation / 2.1: debenzylation / 3.1: glycosulation / 3.2: Reduction;
DOI:10.1021/jo000911r