methyl 2-O-acetyl-6-O-(2-(azidomethyl)benzoyl)-3,4-di-O-benzyl-β-D-glucopyranoside

Base Information

Chemical Name:methyl 2-O-acetyl-6-O-(2-(azidomethyl)benzoyl)-3,4-di-O-benzyl-β-D-glucopyranoside
CAS No.:385421-92-1
Molecular Formula:C₃₁H₃₃N₃O₈
Molecular Weight:575.618
Hs Code.:

Synonyms:methyl 2-O-acetyl-6-O-(2-(azidomethyl)benzoyl)-3,4-di-O-benzyl-β-D-glucopyranoside

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of methyl 2-O-acetyl-6-O-(2-(azidomethyl)benzoyl)-3,4-di-O-benzyl-β-D-glucopyranoside

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Technology Process of methyl 2-O-acetyl-6-O-(2-(azidomethyl)benzoyl)-3,4-di-O-benzyl-β-D-glucopyranoside

There total 11 articles about methyl 2-O-acetyl-6-O-(2-(azidomethyl)benzoyl)-3,4-di-O-benzyl-β-D-glucopyranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

: 108-24-7
acetic anhydride

: 373606-22-5
methyl 6-O-(2-(azidomethyl)benzoyl)-3,4-di-O-benzyl-β-D-glucopyranoside

: 385421-92-1
methyl 2-O-acetyl-6-O-(2-(azidomethyl)benzoyl)-3,4-di-O-benzyl-β-D-glucopyranoside

Guidance literature:: With dmap; In dichloromethane; at 20 ℃; for 1h;
DOI:10.1021/jo015987h

Reference yield:

: 2417-73-4
methyl 2-bromomethylbenzoate

: 385421-92-1
methyl 2-O-acetyl-6-O-(2-(azidomethyl)benzoyl)-3,4-di-O-benzyl-β-D-glucopyranoside

Guidance literature:: Multi-step reaction with 4 steps

1: 4.58 g / NaN₃ / ethanol / 48 h / 20 °C

2: 97 percent / LiOH*H₂O; H₂O / tetrahydrofuran / 60 h / 20 °C

3: 97 percent / thionyl chloride / CHCl₃ / 5 h / Heating

4: DMAP / CH₂Cl₂ / 0.17 h / 20 °C

With dmap; lithium hydroxide; thionyl chloride; sodium azide; water; In tetrahydrofuran; ethanol; dichloromethane; chloroform;
DOI:10.1021/jo015987h

Reference yield:

: 89-71-4
2-Methyl-benzoic acid methyl ester

: 385421-92-1
methyl 2-O-acetyl-6-O-(2-(azidomethyl)benzoyl)-3,4-di-O-benzyl-β-D-glucopyranoside

Guidance literature:: Multi-step reaction with 5 steps

1: NBS / benzoyl peroxide / CCl₄ / 24 h / Heating

2: 4.58 g / NaN₃ / ethanol / 48 h / 20 °C

3: 97 percent / LiOH*H₂O; H₂O / tetrahydrofuran / 60 h / 20 °C

4: 97 percent / thionyl chloride / CHCl₃ / 5 h / Heating

5: DMAP / CH₂Cl₂ / 0.17 h / 20 °C

With dmap; lithium hydroxide; N-Bromosuccinimide; thionyl chloride; sodium azide; water; dibenzoyl peroxide; In tetrahydrofuran; tetrachloromethane; ethanol; dichloromethane; chloroform;
DOI:10.1021/jo015987h