4-methyl-N-(2-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)allyl)benzenesulfonamide

Base Information

Chemical Name:4-methyl-N-(2-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)allyl)benzenesulfonamide
CAS No.:1294009-06-5
Molecular Formula:C₁₆H₂₄BNO₄S
Molecular Weight:337.248
Hs Code.:

Synonyms:4-methyl-N-(2-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)allyl)benzenesulfonamide

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of 4-methyl-N-(2-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)allyl)benzenesulfonamide

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Technology Process of 4-methyl-N-(2-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)allyl)benzenesulfonamide

There total 3 articles about 4-methyl-N-(2-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)allyl)benzenesulfonamide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 73.0%

: 55022-46-3
4-methyl-N-prop-2-ynylbenzenesulfonamide

: 73183-34-3
bis(pinacol)diborane

: 1294009-06-5
4-methyl-N-(2-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)allyl)benzenesulfonamide

Guidance literature:: bis(pinacol)diborane; With (1,3-dimesitylimidazolidin-2-yl)copper(I) chloride; sodium t-butanolate; In tetrahydrofuran; at 22 ℃; for 0.5h; Inert atmosphere;

4-methyl-N-prop-2-ynylbenzenesulfonamide; With methanol; In tetrahydrofuran; at -50 ℃; for 24h; regioselective reaction; Inert atmosphere;
DOI:10.1021/ja2007643

Reference yield: 70.0%

: 55022-46-3
4-methyl-N-prop-2-ynylbenzenesulfonamide

: 73183-34-3
bis(pinacol)diborane

: 1294009-24-7
(E)-4-methyl-N-(3-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)allyl)benzenesulfonamide

: 1294009-06-5
4-methyl-N-(2-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)allyl)benzenesulfonamide

Guidance literature:: bis(pinacol)diborane; With [1,3-bis(1-adamantyl)imidazolidin-2-yl]chloro-copper; sodium t-butanolate; In tetrahydrofuran; at 22 ℃; for 0.5h; Inert atmosphere;

4-methyl-N-prop-2-ynylbenzenesulfonamide; With methanol; In tetrahydrofuran; at 22 ℃; for 12h; regioselective reaction; Inert atmosphere;
DOI:10.1021/ja2007643

Reference yield:

: 55022-46-3
4-methyl-N-prop-2-ynylbenzenesulfonamide

: 73183-34-3
bis(pinacol)diborane

: 1294009-06-5
4-methyl-N-(2-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)allyl)benzenesulfonamide

: C₁₆H₂₄BNO₄S

Guidance literature:: With chloro[1,3-bis(2,4,6-trimethylphenyl)imidazol-2-ylidene]copper(I); SPGS-550M; sodium hydroxide; In water; at 20 ℃; for 20h; Overall yield = 60 %Spectr.; regioselective reaction; Green chemistry;
DOI:10.1002/adsc.201700094