6-(p-carbethoxybenzyl)-3,3,10,10-tetramethyl-1,2-dithia-5,8-diazacyclodeca-4,8-diene

Base Information

Chemical Name:6-(p-carbethoxybenzyl)-3,3,10,10-tetramethyl-1,2-dithia-5,8-diazacyclodeca-4,8-diene
CAS No.:300765-96-2
Molecular Formula:C₂₀H₂₈N₂O₂S₂
Molecular Weight:392.587
Hs Code.:

Synonyms:6-(p-carbethoxybenzyl)-3,3,10,10-tetramethyl-1,2-dithia-5,8-diazacyclodeca-4,8-diene

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Chemical Property of 6-(p-carbethoxybenzyl)-3,3,10,10-tetramethyl-1,2-dithia-5,8-diazacyclodeca-4,8-diene

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Technology Process of 6-(p-carbethoxybenzyl)-3,3,10,10-tetramethyl-1,2-dithia-5,8-diazacyclodeca-4,8-diene

There total 5 articles about 6-(p-carbethoxybenzyl)-3,3,10,10-tetramethyl-1,2-dithia-5,8-diazacyclodeca-4,8-diene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 68.0%

: 15581-80-3
2,2'-dithiobis(2-methylpropanal)

: 1-(p-carbethoxybenzyl)ethylenediamine dihydrochloride

: 300765-96-2
6-(p-carbethoxybenzyl)-3,3,10,10-tetramethyl-1,2-dithia-5,8-diazacyclodeca-4,8-diene

Guidance literature:: With bis-(trimethylsilyl)acetamide; In benzene; at 70 - 80 ℃; for 3h;
DOI:10.1016/S0040-4020(00)00424-5

Reference yield:

: 2-(p-carbomethoxybenzylidine)-2-benzamidoacetonitrile

: 300765-96-2
6-(p-carbethoxybenzyl)-3,3,10,10-tetramethyl-1,2-dithia-5,8-diazacyclodeca-4,8-diene

Guidance literature:: Multi-step reaction with 4 steps

1: H₂; NH₃ / Raney Nickel / ethanol / 20 h / 20 °C / 2585.74 - 2844.31 Torr

2: conc. HCl / 48 h / Heating

3: 1.98 g / HCl(gas) / 16 h

4: 68 percent / bis-trimethylsilyl acetamide / benzene / 3 h / 70 - 80 °C

With hydrogenchloride; ammonia; hydrogen; bis-(trimethylsilyl)acetamide; nickel; In ethanol; benzene; 1: Catalytic hydrogenation / 2: Hydrolysis / 3: Esterification / 4: cyclocondensation;
DOI:10.1016/S0040-4020(00)00424-5

Reference yield:

: 4-[5-Imino-2-phenyl-oxazol-(4E)-ylidenemethyl]-benzoic acid methyl ester; hydrochloride

: 300765-96-2
6-(p-carbethoxybenzyl)-3,3,10,10-tetramethyl-1,2-dithia-5,8-diazacyclodeca-4,8-diene

Guidance literature:: Multi-step reaction with 5 steps

1: 2.9 g / Na₂CO₃; H₂O / 2 h / 0 °C

2: H₂; NH₃ / Raney Nickel / ethanol / 20 h / 20 °C / 2585.74 - 2844.31 Torr

3: conc. HCl / 48 h / Heating

4: 1.98 g / HCl(gas) / 16 h

5: 68 percent / bis-trimethylsilyl acetamide / benzene / 3 h / 70 - 80 °C

With hydrogenchloride; ammonia; water; hydrogen; sodium carbonate; bis-(trimethylsilyl)acetamide; nickel; In ethanol; benzene; 1: Hydrolysis / 2: Catalytic hydrogenation / 3: Hydrolysis / 4: Esterification / 5: cyclocondensation;
DOI:10.1016/S0040-4020(00)00424-5