4-(14-(tert-butyldimethylsilyloxy)tetradecyl)-3,5-dimethoxybenzaldehyde

Base Information

Chemical Name:4-(14-(tert-butyldimethylsilyloxy)tetradecyl)-3,5-dimethoxybenzaldehyde
CAS No.:947735-96-8
Molecular Formula:C₂₉H₅₂O₄Si
Molecular Weight:492.815
Hs Code.:

Synonyms:4-(14-(tert-butyldimethylsilyloxy)tetradecyl)-3,5-dimethoxybenzaldehyde

Suppliers and Price of 4-(14-(tert-butyldimethylsilyloxy)tetradecyl)-3,5-dimethoxybenzaldehyde

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of 4-(14-(tert-butyldimethylsilyloxy)tetradecyl)-3,5-dimethoxybenzaldehyde

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of 4-(14-(tert-butyldimethylsilyloxy)tetradecyl)-3,5-dimethoxybenzaldehyde

There total 5 articles about 4-(14-(tert-butyldimethylsilyloxy)tetradecyl)-3,5-dimethoxybenzaldehyde which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 85.0%

: 947735-95-7
(4-(14-(tert-butyldimethylsilyloxy)tetradecyl)-3,5-dimethoxyphenyl)methanol

: 947735-96-8
4-(14-(tert-butyldimethylsilyloxy)tetradecyl)-3,5-dimethoxybenzaldehyde

Guidance literature:: With 4-methyl-morpholine; tetrapropylammonium perruthennate; In dichloromethane; at 0 - 20 ℃; Molecular sieve;

Reference yield:

: tert-butyl(tetradec-13-ynyloxy)dimethylsilane

: 947735-96-8
4-(14-(tert-butyldimethylsilyloxy)tetradecyl)-3,5-dimethoxybenzaldehyde

Guidance literature:: Multi-step reaction with 4 steps

1: Et₃N; CuI / PdCl₂(PPh₃)2 / 80 °C

2: H₂ / Pd/C / ethanol / 24 h / 20 °C

3: LiAlH₄ / tetrahydrofuran / 2 h / 0 - 20 °C

4: TPAP; NMO / CH₂Cl₂ / 1 h / 0 - 20 °C

With copper(l) iodide; lithium aluminium tetrahydride; N-methyl-2-indolinone; tetrapropylammonium perruthennate; hydrogen; triethylamine; bis-triphenylphosphine-palladium(II) chloride; palladium on activated charcoal; In tetrahydrofuran; ethanol; dichloromethane; 1: Sonogashira cross-coupling / 4: Ley oxidation;
DOI:10.1016/j.bmcl.2007.05.037

Reference yield:

: 947735-93-5
Methyl 4-(14-(tert-butyldimethylsilyloxy)tetradec-1-ynyl)-3,5-dimethoxybenzoate

: 947735-96-8
4-(14-(tert-butyldimethylsilyloxy)tetradecyl)-3,5-dimethoxybenzaldehyde

Guidance literature:: Multi-step reaction with 3 steps

1: H₂ / Pd/C / ethanol / 24 h / 20 °C

2: LiAlH₄ / tetrahydrofuran / 2 h / 0 - 20 °C

3: TPAP; NMO / CH₂Cl₂ / 1 h / 0 - 20 °C

With lithium aluminium tetrahydride; N-methyl-2-indolinone; tetrapropylammonium perruthennate; hydrogen; palladium on activated charcoal; In tetrahydrofuran; ethanol; dichloromethane; 3: Ley oxidation;
DOI:10.1016/j.bmcl.2007.05.037