Re(C₅H₅)(NO)(P(C₆H₅)3)(CHCH₃(C₆H₅))

Base Information

Chemical Name:Re(C₅H₅)(NO)(P(C₆H₅)3)(CHCH₃(C₆H₅))
CAS No.:82399-54-0
Molecular Formula:C₃₁H₂₉NOPRe
Molecular Weight:648.758
Hs Code.:

Re(C<sub>5</sub>H<sub>5</sub>)(NO)(P(C<sub>6</sub>H<sub>5</sub>)3)(CHCH<sub>3</sub>(C<sub>6</sub>H<sub>5</sub>))

Synonyms:Re(C₅H₅)(NO)(P(C₆H₅)3)(CHCH₃(C₆H₅))

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Chemical Property of Re(C₅H₅)(NO)(P(C₆H₅)3)(CHCH₃(C₆H₅))

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Technology Process of Re(C₅H₅)(NO)(P(C₆H₅)3)(CHCH₃(C₆H₅))

There total 3 articles about Re(C₅H₅)(NO)(P(C₆H₅)3)(CHCH₃(C₆H₅)) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 84.0%

: 74561-64-1
C₅H₅Re(NO)CHC₆H₅P(C₆H₅)3⁽¹⁺⁾*PF₆^(1-)=Re(C₅H₅)NOP(C₆H₅)3CHC₆H₅PF₆

: 917-54-4
methyllithium

: 82399-54-0
C₅H₅Re(NO)CHCH₃C₆H₅P(C₆H₅)3

Guidance literature:: In diethyl ether; dichloromethane; Re-complex was dissolved in CH2Cl2 under N2, cooled to -78°C, CH3Li in ether was added dropwise, soln. was allowed to warm to room temp.; solvent was removed under vac., residue extd. with benzene, filtered through silica gel, benzene was removed by rotary evaporator, chromd. on silica gel column (CH2Cl2/hexane), collected, solvent was removed in vac.;
DOI:10.1021/ja00382a021

Reference yield: 76.0%

: synclinal-{(η5-C5H5)Re(NO)(PPh3)(CHCH3)}PF6

: 100-58-3
phenylmagnesium bromide

: 82399-54-0
Re(C₅H₅)(NO)(P(C₆H₅)3)(CHCH₃(C₆H₅))

Guidance literature:: In not given; Re-complex was reacted with C6H5MgBr;
DOI:10.1021/ja00353a020

Reference yield:

: 74540-78-6
C₅H₅Re(NO)CHC₆H₅P(C₆H₅)3⁽¹⁺⁾*PF₆^(1-)=Re(C₅H₅)NOP(C₆H₅)3CHC₆H₅PF₆

: 917-54-4
methyllithium

: 82374-39-8
C₅H₅Re(NO)CH(CH₃)C₆H₅P(C₆H₅)3

: 82399-54-0
C₅H₅Re(NO)CHCH₃C₆H₅P(C₆H₅)3

Guidance literature:: In diethyl ether; to -78°C soln. of Re-complex was added dropwise CH3Li in ether, after 15 min at -78°C mixt. was allowed to warm to room temp. under N2; residue extd. with benzene/CH2Cl2, filtered through silica gel, solventwas removed, residue chromd. on silica gel column (CH2Cl2/hexane), collected, solvent was removed; detd. by NMR;
DOI:10.1021/ja00382a021