1,11-bis{3-[1-(4-acetoxyphenyl)-2,2,2-trifluoroethoxysulfonyl]propyl}-3,4,8,9,10,11-hexahydro-2H-13-oxa-6,11-diaza-1-azonia-pentacene tetrafluoroborate

Base Information

Chemical Name:1,11-bis{3-[1-(4-acetoxyphenyl)-2,2,2-trifluoroethoxysulfonyl]propyl}-3,4,8,9,10,11-hexahydro-2H-13-oxa-6,11-diaza-1-azonia-pentacene tetrafluoroborate
CAS No.:1345614-80-3
Molecular Formula:BF₄*C₄₄H₄₄F₆N₃O₁₁S₂
Molecular Weight:1055.77
Hs Code.:

1,11-bis{3-[1-(4-acetoxyphenyl)-2,2,2-trifluoroethoxysulfonyl]propyl}-3,4,8,9,10,11-hexahydro-2H-13-oxa-6,11-diaza-1-azonia-pentacene tetrafluoroborate

Synonyms:1,11-bis{3-[1-(4-acetoxyphenyl)-2,2,2-trifluoroethoxysulfonyl]propyl}-3,4,8,9,10,11-hexahydro-2H-13-oxa-6,11-diaza-1-azonia-pentacene tetrafluoroborate

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Chemical Property of 1,11-bis{3-[1-(4-acetoxyphenyl)-2,2,2-trifluoroethoxysulfonyl]propyl}-3,4,8,9,10,11-hexahydro-2H-13-oxa-6,11-diaza-1-azonia-pentacene tetrafluoroborate

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Technology Process of 1,11-bis{3-[1-(4-acetoxyphenyl)-2,2,2-trifluoroethoxysulfonyl]propyl}-3,4,8,9,10,11-hexahydro-2H-13-oxa-6,11-diaza-1-azonia-pentacene tetrafluoroborate

There total 10 articles about 1,11-bis{3-[1-(4-acetoxyphenyl)-2,2,2-trifluoroethoxysulfonyl]propyl}-3,4,8,9,10,11-hexahydro-2H-13-oxa-6,11-diaza-1-azonia-pentacene tetrafluoroborate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 46.0%

: 1345614-77-8
acetic acid 4-(1{3-[7-(tert-butyldimethylsilanyloxy)-3,4-dihydro-2H-quinolin-1-yl]propane-1-sulfonyloxy}-2,2,2-trifluoroethyl)phenyl ester

: 1345614-68-7
acetic acid 4-(2,2,2-trifluoro-1-{3-[7-methoxy-6-(4-nitrophenylazo)-3,4-dihydro-2H-quinolin-1-yl]propane-1-sulfonyloxy}ethyl)phenyl ester

: 1345614-80-3
1,11-bis{3-[1-(4-acetoxyphenyl)-2,2,2-trifluoroethoxysulfonyl]propyl}-3,4,8,9,10,11-hexahydro-2H-13-oxa-6,11-diaza-1-azonia-pentacene tetrafluoroborate

Guidance literature:: In acetic acid; at 80 ℃; for 2.5h;
DOI:10.1021/ol202619f

Reference yield:

: 1279691-41-6
acetic acid 4-(2,2,2-trifluoro-1-hydroxyethyl)phenyl ester

: 1345614-80-3
1,11-bis{3-[1-(4-acetoxyphenyl)-2,2,2-trifluoroethoxysulfonyl]propyl}-3,4,8,9,10,11-hexahydro-2H-13-oxa-6,11-diaza-1-azonia-pentacene tetrafluoroborate

Guidance literature:: Multi-step reaction with 5 steps

1: triethylamine / dichloromethane / 1 h / 0 °C

2: sodium iodide / acetone / 17 h / Reflux

3: potassium carbonate / N,N-dimethyl-formamide / 65 °C

4: sulfuric acid / methanol; water / 1 h / 20 °C

5: acetic acid / 2.5 h / 80 °C

With sulfuric acid; potassium carbonate; triethylamine; sodium iodide; In methanol; dichloromethane; water; acetic acid; N,N-dimethyl-formamide; acetone;
DOI:10.1021/ol202619f

Reference yield:

: 1345614-61-0
acetic acid 4-[1-(3-chloropropane-1-sulfonyloxy)-2,2,2-trifluoroethyl]phenyl ester

: 1345614-80-3
1,11-bis{3-[1-(4-acetoxyphenyl)-2,2,2-trifluoroethoxysulfonyl]propyl}-3,4,8,9,10,11-hexahydro-2H-13-oxa-6,11-diaza-1-azonia-pentacene tetrafluoroborate

Guidance literature:: Multi-step reaction with 4 steps

1: sodium iodide / acetone / 17 h / Reflux

2: potassium carbonate / N,N-dimethyl-formamide / 65 °C

3: sulfuric acid / methanol; water / 1 h / 20 °C

4: acetic acid / 2.5 h / 80 °C

With sulfuric acid; potassium carbonate; sodium iodide; In methanol; water; acetic acid; N,N-dimethyl-formamide; acetone;
DOI:10.1021/ol202619f