Ph₂C₅H₂O(CH(ferrocenyl))

Base Information

• Chemical Name: Ph₂C₅H₂O(CH(ferrocenyl))
• CAS No.: 1091631-82-1
• Molecular Formula: C₂₈H₂₂FeO
• Molecular Weight: 430.329
• Mol file: 1091631-82-1.mol

Synonyms:Ph₂C₅H₂O(CH(ferrocenyl))

Chemical Property of Ph₂C₅H₂O(CH(ferrocenyl))

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

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Technology Process of Ph₂C₅H₂O(CH(ferrocenyl))

There total 4 articles about Ph₂C₅H₂O(CH(ferrocenyl)) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 66.0%

[Ph2C5H2OCH(ferrocenyl)CH(ferrocenyl)C5H2OPh2](PF6)2 → Ph2C5H2O(CH(ferrocenyl)) (1091631-82-1)

Guidance literature:

With Zn; In dichloromethane; acetic acid; treatment of bispyrylium deriv. with zinc in acetic acid/CH2Cl2 mixt.;

DOI:10.1021/om800638q

Reference yield: 65.0%

ferrocenecarboxaldehyde (12093-10-6) + 2,6-diphenyl-4H-pyran-4-yl triphenylphosphonium tetrafluoroborate salt → Ph2C5H2O(CH(ferrocenyl)) (1091631-82-1)

Guidance literature:

With n-butyllithium; In tetrahydrofuran; hexane; under N2 using standard Schlenk technique; n-BuLi in hexanes added dropwise at -78°C under N2 to THF soln. of pyran deriv.; after 5 min, 1 equiv. of Fc deriv. added; stirred at room temp. for 1 h; poured into cold water; extd. with ether, dried over MgSO4; evapd. under vac.; purified by chromy. on silica gel (eluent ether-petroleum ether);

DOI:10.1016/j.jorganchem.2009.10.006

Reference yield: 50.0%

[Ph2C5H2OC(ferrocenyl)C(ferrocenyl)C5H2OPh2](PF6)2 → Ph2C5H2O(CH(ferrocenyl)) (1091631-82-1) + [Ph2C5H2OC(ferrocenyl)C(ferrocenyl)C5H2OPh2]

Guidance literature:

With Zn; In dichloromethane; acetic acid; treatment of pyrylium salt with zinc in acetic acid/CH2Cl2 mixt.;

DOI:10.1021/om800638q

upstream raw materials:

ferrocenecarboxaldehyde

Downstream raw materials:

(C₅H₅)Fe(C₅H₄C(CHO)C₅H₂O(C₆H₅)2)

1-acetyl-1'-[(2,6-diphenyl-4H-pyran-4-ylidene)methyl]ferrocene