1-acetyl-1'-[(2,6-diphenyl-4H-pyran-4-ylidene)methyl]ferrocene

Base Information

• Chemical Name: 1-acetyl-1'-[(2,6-diphenyl-4H-pyran-4-ylidene)methyl]ferrocene
• CAS No.: 1610840-56-6
• Molecular Formula: C₃₀H₂₄FeO₂
• Molecular Weight: 472.366
• Mol file: 1610840-56-6.mol

Synonyms:1-acetyl-1'-[(2,6-diphenyl-4H-pyran-4-ylidene)methyl]ferrocene

Chemical Property of 1-acetyl-1'-[(2,6-diphenyl-4H-pyran-4-ylidene)methyl]ferrocene

Chemical Property:

Purity/Quality:

Safty Information:

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Technology Process of 1-acetyl-1'-[(2,6-diphenyl-4H-pyran-4-ylidene)methyl]ferrocene

There total 1 articles about 1-acetyl-1'-[(2,6-diphenyl-4H-pyran-4-ylidene)methyl]ferrocene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 61.0%

Ph2C5H2O(CH(ferrocenyl)) (1091631-82-1) + acetyl chloride (75-36-5) → 1-acetyl-1'-[(2,6-diphenyl-4H-pyran-4-ylidene)methyl]ferrocene (1610840-56-6)

Guidance literature:

acetyl chloride; With aluminum (III) chloride; In dichloromethane; at 20 ℃; for 2h; Schlenk technique;

Ph₂C₅H₂O(CH(ferrocenyl)); In dichloromethane; at 0 ℃; for 2h; Schlenk technique; Inert atmosphere;

DOI:10.1016/j.jorganchem.2014.03.029

Reference yield:

1-acetyl-1'-[(2,6-diphenyl-4H-pyran-4-ylidene)methyl]ferrocene (1610840-56-6) + ethyl acetate (141-78-6) → C32H26FeO3 + 1-(1,3-dioxobutyl)-1'-[(2,6-diphenyl-4H-pyran-4-ylidene)methyl]ferrocene (1610840-57-7)

Guidance literature:

1-acetyl-1'-[(2,6-diphenyl-4H-pyran-4-ylidene)methyl]ferrocene; With n-butyllithium; diisopropylamine; In diethyl ether; at 0 - 20 ℃; Schlenk technique;

ethyl acetate; In diethyl ether; at 0 - 20 ℃; Overall yield = 20 %; Overall yield = 105 mg; Schlenk technique;

DOI:10.1016/j.jorganchem.2014.03.029

upstream raw materials:

Ph₂C₅H₂O(CH(ferrocenyl))

acetyl chloride

Downstream raw materials:

1-(1,3-dioxobutyl)-1'-[(2,6-diphenyl-4H-pyran-4-ylidene)methyl]ferrocene