Technology Process of [Zn(NC4H2)3(C(C6H5))4NC4N2C12H6N2]
There total 7 articles about [Zn(NC4H2)3(C(C6H5))4NC4N2C12H6N2] which
guide to synthetic route it.
The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:
synthetic route:
- Guidance literature:
-
C56H34N8;
With
zinc diacetate;
In
methanol; dichloromethane;
for 12h;
Inert atmosphere;
Reflux;
With
sodium acetate; edetate disodium; acetic acid;
In
dichloromethane; water;
at 20 ℃;
for 24h;
pH=4.7;
DOI:10.1016/j.ica.2010.07.008
- Guidance literature:
-
With
EDTA;
In
ethanol; dichloromethane;
under N2; Zn(OAc)2 soln. (MeOH) added to (HNC4H2)2(NC4H2)(CC6H5)4(NC4)N2C12H6N2 (0.0708 mmol) soln. (CH2Cl2), reflux (12 h), solvent removed (vac.), residue dissolved (CH2Cl2), washed (H2O), organic layer added to EDTA soln., stirred (24 h, room temp.); organic layer sepd., washed with sodium bicarbonate soln., dried, concd.; elem. anal.;
DOI:10.1016/j.ica.2010.07.008
- Guidance literature:
-
Multi-step reaction with 5 steps
1.1: acetic anhydride; copper(II) nitrate / dichloromethane / 20 h / 20 °C / Inert atmosphere
2.1: sulfuric acid / dichloromethane / 0.13 h / 20 °C / Inert atmosphere
3.1: hydrogenchloride; tin(ll) chloride / dichloromethane; water / 0.5 h / 60 °C / Inert atmosphere; Microwave irradiation
3.2: 1 h / Inert atmosphere; UV-irradiation
4.1: trifluoroacetic acid / dichloromethane / 24 h / Inert atmosphere; Reflux
5.1: zinc diacetate / methanol; dichloromethane / 12 h / Inert atmosphere; Reflux
5.2: 24 h / 20 °C / pH 4.7
With
hydrogenchloride; sulfuric acid; zinc diacetate; acetic anhydride; copper(II) nitrate; trifluoroacetic acid; tin(ll) chloride;
In
methanol; dichloromethane; water;
DOI:10.1016/j.ica.2010.07.008
