2,3,4,6-tetra-O-benzyl-1-O-(trifluoroacetyl)-α-D-glucopyranose

Base Information

• Chemical Name: 2,3,4,6-tetra-O-benzyl-1-O-(trifluoroacetyl)-α-D-glucopyranose
• CAS No.: 125343-69-3
• Molecular Formula: C₃₆H₃₅F₃O₇
• Molecular Weight: 636.665
• Mol file: 125343-69-3.mol

Synonyms:2,3,4,6-tetra-O-benzyl-1-O-(trifluoroacetyl)-α-D-glucopyranose

Chemical Property of 2,3,4,6-tetra-O-benzyl-1-O-(trifluoroacetyl)-α-D-glucopyranose

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 2,3,4,6-tetra-O-benzyl-1-O-(trifluoroacetyl)-α-D-glucopyranose

There total 2 articles about 2,3,4,6-tetra-O-benzyl-1-O-(trifluoroacetyl)-α-D-glucopyranose which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

2,3,4,6-tetra-O-benzyl-D-glucopyranose (6564-72-3) + trifluoroacetic anhydride (407-25-0) → 2,3,4,6-tetra-O-benzyl-1-O-(trifluoroacetyl)-α-D-glucopyranose (125343-69-3)

Guidance literature:

With sodium 2,2,2-trifluoroacetate; for 0.5h; Heating;

DOI:10.1016/0008-6215(89)85052-9

Reference yield:

2,3,4,6-Tetra-O-benzyl-D-glucopyranose (4291-69-4,6386-24-9,6564-72-3,59531-24-7,69257-52-9,78184-89-1,78609-16-2,78609-17-3,78609-18-4,96553-53-6,104111-61-7,131347-08-5,4132-28-9) + trifluoroacetic anhydride (407-25-0) → 2,3,4,6-tetra-O-benzyl-1-O-(trifluoroacetyl)-α-D-glucopyranose (125343-69-3)

Guidance literature:

In 1,2-dichloro-ethane; for 4h; Yield given;

DOI:10.1039/a705145j

Reference yield: 99.0%

1,2,3-trimethoxybenzene (621-23-8) + 2,3,4,6-tetra-O-benzyl-1-O-(trifluoroacetyl)-α-D-glucopyranose (125343-69-3) → 1-deoxy-1-(C-2',4',6'-trimethoxyphenyl) 2,3,4,6-tetra-O-benzyl-β-D-glucopyranoside (82300-67-2)

Guidance literature:

With boron trifluoride diethyl etherate; In dichloromethane; for 0.0833333h; Ambient temperature;

DOI:10.1016/0008-6215(89)85052-9

upstream raw materials:

2,3,4,6-tetra-O-benzyl-D-glucopyranose

trifluoroacetic anhydride

2,3,4,6-Tetra-O-benzyl-D-glucopyranose

Downstream raw materials:

1-deoxy-1-(C-2',4',6'-trimethoxyphenyl) 2,3,4,6-tetra-O-benzyl-β-D-glucopyranoside

2,4-dihydroxy-1-(2,3,4,6-tetra-O-benzyl-β-D-glucopyranosyl)-benzene

2,4-dihydroxy-1-(2,3,4,6-tetra-O-benzyl-α-D-glucopyranosyl)-benzene

2,3,4,6-tetra-O-benzyl-1-deoxy-1-(4-methoxyphenyl)-β-D-glucopyranose