[Os(IV)2(μ-O)(μ-acetato)2Cl4(triphenylarsine)2]

Base Information

• Chemical Name: [Os(IV)2(μ-O)(μ-acetato)2Cl4(triphenylarsine)2]
• CAS No.: 565430-18-4
• Molecular Formula: C₄₀H₃₆As₂Cl₄O₅Os₂
• Molecular Weight: 1268.78
• Mol file: 565430-18-4.mol

Synonyms:[Os(IV)2(μ-O)(μ-acetato)2Cl4(triphenylarsine)2]

Chemical Property of [Os(IV)2(μ-O)(μ-acetato)2Cl4(triphenylarsine)2]

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [Os(IV)2(μ-O)(μ-acetato)2Cl4(triphenylarsine)2]

There total 2 articles about [Os(IV)2(μ-O)(μ-acetato)2Cl4(triphenylarsine)2] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 70.0%

trans-[osmium(VI)O2Cl2(AsPh3)2] + acetic acid (64-19-7,77671-22-8) → [Os(IV)2(μ-O)(μ-acetato)2Cl4(triphenylarsine)2] (565430-18-4) + triphenylarsineoxide (1153-05-5,856568-31-5)

Guidance literature:

With pentane or hexane; In chloroform; acetic acid; byproducts: H2O; suspn. of trans-(OsO2(AsPh3)2Cl2) boiled in glacial acetic acid; solventevapd. and dry residue dissolved in CHCl3; minor amt. of pentane or hex ane added to soln.; ppt. filtered off, washed with ether and dried over KOH; elem. anal.;

DOI:10.1023/A:1023366810613

Reference yield: 70.0%

trans-[osmium(VI)O2Cl2(AsPh3)2] + acetic acid (64-19-7,77671-22-8) → [Os(IV)2(μ-O)(μ-acetato)2Cl4(triphenylarsine)2] (565430-18-4)

Guidance literature:

In acetic acid; suspn. of trans-(OsO2(AsPh3)2Cl2) in glacial acetic acid heated under reflux until complete dissolution; evapd. on air bath, residue dissolved in CHCl3, pentane added, ppt. filtered off, washed with ether, stored in desiccator over KOH, dissolved inmin. amt. of CHCl3, column chromy. (silipore 600(GC)), concd. at room t emp., dried under vac.; elem. anal.;

DOI:10.1023/B:RUCO.0000022807.77697.ee

Reference yield:

[Os(IV)2(μ-O)(μ-acetato)2Cl4(triphenylarsine)2] (565430-18-4) → [Os2(μ-OH)(μ-O2CCH3)2(AsPh3)2Cl4](1+)

Guidance literature:

With HClO₄; In perchloric acid; aq. HClO4; osmium complex react with HClO4; compd. not isolated; detn. by UV/vis spectroscopy;

DOI:10.1023/A:1023366810613

upstream raw materials:

acetic acid