(2S,3R,5R)-3-Azido-2-benzyloxy-5-hydroxycyclohexanone ethylene dithioacetal

Base Information

Chemical Name:(2S,3R,5R)-3-Azido-2-benzyloxy-5-hydroxycyclohexanone ethylene dithioacetal
CAS No.:171074-27-4
Molecular Formula:C₁₅H₁₉N₃O₂S₂
Molecular Weight:337.467
Hs Code.:

Synonyms:(2S,3R,5R)-3-Azido-2-benzyloxy-5-hydroxycyclohexanone ethylene dithioacetal

Suppliers and Price of (2S,3R,5R)-3-Azido-2-benzyloxy-5-hydroxycyclohexanone ethylene dithioacetal

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of (2S,3R,5R)-3-Azido-2-benzyloxy-5-hydroxycyclohexanone ethylene dithioacetal

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of (2S,3R,5R)-3-Azido-2-benzyloxy-5-hydroxycyclohexanone ethylene dithioacetal

There total 5 articles about (2S,3R,5R)-3-Azido-2-benzyloxy-5-hydroxycyclohexanone ethylene dithioacetal which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 69.0%

: 540-63-6
ethane-1,2-dithiol

: 171074-21-8
(2S,3R,5R)-3-Azido-2-benzyloxy-5-hydroxycyclohexanone

: 171074-27-4
(2S,3R,5R)-3-Azido-2-benzyloxy-5-hydroxycyclohexanone ethylene dithioacetal

Guidance literature:: With boron trifluoride diethyl etherate; In dichloromethane; for 1h; Ambient temperature;
DOI:10.7164/antibiotics.48.683

Reference yield:

: 100-39-0
benzyl bromide

: 171074-27-4
(2S,3R,5R)-3-Azido-2-benzyloxy-5-hydroxycyclohexanone ethylene dithioacetal

Guidance literature:: Multi-step reaction with 3 steps

1: 88 percent / NaH / dimethylformamide / 1.) 0 deg C, 40 min, 2.) 25 deg C, 16 h

2: 57 percent / Hg(OOCCF₃)2 / acetone; H₂O / 3 h

3: 69 percent / BF₃*Et₂O / CH₂Cl₂ / 1 h / Ambient temperature

With boron trifluoride diethyl etherate; mercury(II) trifluoroacetate; sodium hydride; In dichloromethane; water; N,N-dimethyl-formamide; acetone;
DOI:10.7164/antibiotics.48.683

Reference yield:

: 98383-20-1
methyl 3-azido-6-bromo-2,3,6-trideoxy-α-D-arabino-hexopyranoside

: 171074-27-4
(2S,3R,5R)-3-Azido-2-benzyloxy-5-hydroxycyclohexanone ethylene dithioacetal

Guidance literature:: Multi-step reaction with 3 steps

1: 88 percent / NaH / dimethylformamide / 1.) 0 deg C, 40 min, 2.) 25 deg C, 16 h

2: 57 percent / Hg(OOCCF₃)2 / acetone; H₂O / 3 h

3: 69 percent / BF₃*Et₂O / CH₂Cl₂ / 1 h / Ambient temperature

With boron trifluoride diethyl etherate; mercury(II) trifluoroacetate; sodium hydride; In dichloromethane; water; N,N-dimethyl-formamide; acetone;
DOI:10.7164/antibiotics.48.683