N-mesitylpyrrole

Base Information

• Chemical Name: N-mesitylpyrrole
• CAS No.: 881041-55-0
• Molecular Formula: C₁₃H₁₅N
• Molecular Weight: 185.269
• Mol file: 881041-55-0.mol

Synonyms:N-mesitylpyrrole

Chemical Property of N-mesitylpyrrole

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

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Technology Process of N-mesitylpyrrole

There total 1 articles about N-mesitylpyrrole which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

cis,trans-2,5-dimethoxytetrahydrofuran (696-59-3) + 2,4,6-trimethylaniline (88-05-1) → N-mesitylpyrrole (881041-55-0)

Guidance literature:

With hydrogenchloride; iron(III) chloride heptahydrate; In water; at 60 ℃;

DOI:10.1055/s-0029-1217799

Reference yield: 83.0%

N-mesitylpyrrole (881041-55-0) + di(p-tolyl) sulfoxide (1774-35-2) → (C4H3N)(C6H2(CH3)3)(S(C6H4CH3)2)(1+)*B(C6H5)4(1-)=(C4H3N)(C6H2(CH3)3)(S(C6H4CH3)2)B(C6H5)4 (1097213-62-1)

Guidance literature:

N-mesitylpyrrole; di(p-tolyl) sulfoxide; With trifluoroacetic anhydride; In dichloromethane; at 0 - 20 ℃; Inert atmosphere;

With lithium perchlorate; In dichloromethane; at 20 ℃; Inert atmosphere;

With sodium tetraphenyl borate; In methanol; at 20 ℃; for 0.5h; Inert atmosphere;

DOI:10.1039/b813454e

Reference yield: 22.0%

N-mesitylpyrrole (881041-55-0) + di(p-tolyl) sulfoxide (1774-35-2) → C27H28NS(1+)*ClO4(1-) (1097213-61-0) + C27H28NS(1+)*ClO4(1-)

Guidance literature:

N-mesitylpyrrole; di(p-tolyl) sulfoxide; With trifluoroacetic anhydride; In dichloromethane; at 0 - 20 ℃; Inert atmosphere;

With lithium perchlorate; In dichloromethane; at 20 ℃; Inert atmosphere;

DOI:10.1039/b813454e

upstream raw materials:

cis,trans-2,5-dimethoxytetrahydrofuran

2,4,6-trimethylaniline

Downstream raw materials:

1-(2,4,6-trimethyl-phenyl)-1H-pyrrole-3-carbaldehyde

C₂₇H₂₈NS⁽¹⁺⁾*ClO₄^(1-)

(C₄H₃N)(C₆H₂(CH₃)3)(S(C₆H₄CH₃)2)⁽¹⁺⁾*B(C₆H₅)4^(1-)=(C₄H₃N)(C₆H₂(CH₃)3)(S(C₆H₄CH₃)2)B(C₆H₅)4

Refernces

• 1、 Azizi, Najmadin,Davoudpour, Anahita,Eskandari, Farshid,Batebi, Ehlham. "Squaric acid catalyzed simple synthesis of N-substituted pyrroles in green reaction media". . p. 405 - 409. Retrieved 2013/05/09.