2,6-Dichloro-benzoic acid (E)-(S)-3-{1-[dimethyl-(1,1,2-trimethyl-propyl)-silanyloxy]-cyclopropyl}-1-methyl-allyl ester

Base Information

Chemical Name:2,6-Dichloro-benzoic acid (E)-(S)-3-{1-[dimethyl-(1,1,2-trimethyl-propyl)-silanyloxy]-cyclopropyl}-1-methyl-allyl ester
CAS No.:130571-48-1
Molecular Formula:C₂₂H₃₂Cl₂O₃Si
Molecular Weight:443.486
Hs Code.:

Synonyms:2,6-Dichloro-benzoic acid (E)-(S)-3-{1-[dimethyl-(1,1,2-trimethyl-propyl)-silanyloxy]-cyclopropyl}-1-methyl-allyl ester

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Chemical Property of 2,6-Dichloro-benzoic acid (E)-(S)-3-{1-[dimethyl-(1,1,2-trimethyl-propyl)-silanyloxy]-cyclopropyl}-1-methyl-allyl ester

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Technology Process of 2,6-Dichloro-benzoic acid (E)-(S)-3-{1-[dimethyl-(1,1,2-trimethyl-propyl)-silanyloxy]-cyclopropyl}-1-methyl-allyl ester

There total 3 articles about 2,6-Dichloro-benzoic acid (E)-(S)-3-{1-[dimethyl-(1,1,2-trimethyl-propyl)-silanyloxy]-cyclopropyl}-1-methyl-allyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 130571-43-6
(E)-(S)-4-{1-[Dimethyl-(1,1,2-trimethyl-propyl)-silanyloxy]-cyclopropyl}-but-3-en-2-ol

: 4659-45-4
2,6-Dichlorobenzoyl chloride

: 130571-48-1
2,6-Dichloro-benzoic acid (E)-(S)-3-{1-[dimethyl-(1,1,2-trimethyl-propyl)-silanyloxy]-cyclopropyl}-1-methyl-allyl ester

Guidance literature:: With pyridine; In dichloromethane; at 0 ℃; Yield given;
DOI:10.1016/S0040-4039(00)97562-2

Reference yield:

: 130571-40-3
1-[Dimethyl-(1,1,2-trimethyl-propyl)-silanyloxy]-cyclopropanecarbaldehyde

: 130571-48-1
2,6-Dichloro-benzoic acid (E)-(S)-3-{1-[dimethyl-(1,1,2-trimethyl-propyl)-silanyloxy]-cyclopropyl}-1-methyl-allyl ester

Guidance literature:: Multi-step reaction with 2 steps

1: 1.) MeLi / 1.) THF, -78 deg C

2: pyridine / CH₂Cl₂ / 0 °C

With pyridine; methyllithium; In dichloromethane;
DOI:10.1016/S0040-4039(00)97562-2

Reference yield:

: 130571-41-4
(E)-4-{1-[Dimethyl-(1,1,2-trimethyl-propyl)-silanyloxy]-cyclopropyl}-but-3-en-2-one

: 130571-48-1
2,6-Dichloro-benzoic acid (E)-(S)-3-{1-[dimethyl-(1,1,2-trimethyl-propyl)-silanyloxy]-cyclopropyl}-1-methyl-allyl ester

Guidance literature:: Multi-step reaction with 2 steps

1: (R)-(+) binaphthol modified LiAlH₄ (Binal-H)

2: pyridine / CH₂Cl₂ / 0 °C

With pyridine; (R)-(+) binaphthol modified LiAlH₄ (Binal-H); In dichloromethane;
DOI:10.1016/S0040-4039(00)97562-2