trans-{Rh(1,3:4,6-bis(1,4-(6-(1-benzimidazolyl)-1,4-dioxahexyl)-2,3-xylylene)-tetrahydro-3a,6a-diphenylimidazo{4,5-d}imidazole-2,5(1H,3H)-dione)Cl₂}Cl*12H₂O

Base Information

• Chemical Name: trans-{Rh(1,3:4,6-bis(1,4-(6-(1-benzimidazolyl)-1,4-dioxahexyl)-2,3-xylylene)-tetrahydro-3a,6a-diphenylimidazo{4,5-d}imidazole-2,5(1H,3H)-dione)Cl₂}Cl*12H₂O
• CAS No.: 106319-07-7
• Molecular Formula: C₇₆H₇₄Cl₂N₁₂O₁₀Rh*Cl*12H₂O
• Molecular Weight: 1740.95

Synonyms:trans-{Rh(1,3:4,6-bis(1,4-(6-(1-benzimidazolyl)-1,4-dioxahexyl)-2,3-xylylene)-tetrahydro-3a,6a-diphenylimidazo{4,5-d}imidazole-2,5(1H,3H)-dione)Cl₂}Cl*12H₂O

Chemical Property of trans-{Rh(1,3:4,6-bis(1,4-(6-(1-benzimidazolyl)-1,4-dioxahexyl)-2,3-xylylene)-tetrahydro-3a,6a-diphenylimidazo{4,5-d}imidazole-2,5(1H,3H)-dione)Cl₂}Cl*12H₂O

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Technology Process of trans-{Rh(1,3:4,6-bis(1,4-(6-(1-benzimidazolyl)-1,4-dioxahexyl)-2,3-xylylene)-tetrahydro-3a,6a-diphenylimidazo{4,5-d}imidazole-2,5(1H,3H)-dione)Cl₂}Cl*12H₂O

There total 2 articles about trans-{Rh(1,3:4,6-bis(1,4-(6-(1-benzimidazolyl)-1,4-dioxahexyl)-2,3-xylylene)-tetrahydro-3a,6a-diphenylimidazo{4,5-d}imidazole-2,5(1H,3H)-dione)Cl₂}Cl*12H₂O which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 70.0%

benzoimidazole (51-17-2,79351-71-6) + 2-(2-chloroethoxy)ethyl tosylate (64820-21-9) + 5,7,12,13b,13c,14-hexahydro-1,4,8,11-tetrahydroxy-13b,13c-diphenyl-6H,13H-5a,6a,12a,13a-tetraazabenz[5,6]azuleno[2,1,8-ija]benz[f]azulene-6,13-dione (106319-02-2) + rhodium(III)chloride (10049-07-7) → {RhCl2(C6H4NCHN)4(CH2CH2O)8(C6H2C3H4N2CO(C6H5))2}(1+)*Cl(1-)={RhCl2(C6H4NCHN)4(CH2CH2O)8(C6H2C3H4N2CO(C6H5))2}Cl (106319-07-7)

Guidance literature:

With NaH; In dimethyl sulfoxide; N,N-dimethyl-formamide; successive react. of the org. compd. with excess CH3C6H4SO2(OCH2CH2)2Cl and base in DMSO, excess benzimidazole and NaH in DMF, and 1 equiv of RhCl3 in DMSO; elem. anal.;

DOI:10.1021/ja00237a064

Reference yield:

rhodium(III) chloride trihydrate + 1,3:4,6-bis(1,4-(6-(1-benzimidazolyl)-1,4-dioxahexyl)-2,3-xylylene)-tetrahydro-3a,6a-diphenylimidazo{4,5-d}imidazole-2,5(1H,3H,4H,6H)-dione (118715-68-7) → trans-{Rh(1,3:4,6-bis(1,4-(6-(1-benzimidazolyl)-1,4-dioxahexyl)-2,3-xylylene)-tetrahydro-3a,6a-diphenylimidazo{4,5-d}imidazole-2,5(1H,3H)-dione)Cl2}Cl*12H2O (106319-07-7)

Guidance literature:

With hydrogen; In dimethyl sulfoxide; 10 h (20 °C) under nitrogen;

DOI:10.1021/ja00188a022

upstream raw materials:

1,3:4,6-bis(1,4-(6-(1-benzimidazolyl)-1,4-dioxahexyl)-2,3-xylylene)-tetrahydro-3a,6a-diphenylimidazo{4,5-d}imidazole-2,5(1H,3H,4H,6H)-dione

benzoimidazole

2-(2-chloroethoxy)ethyl tosylate

5,7,12,13b,13c,14-hexahydro-1,4,8,11-tetrahydroxy-13b,13c-diphenyl-6H,13H-5a,6a,12a,13a-tetraazabenz[5,6]azuleno[2,1,8-ija]benz[f]azulene-6,13-dione

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