106319-02-2Relevant articles and documents
Synthesis of glycoluril-tetrathiafulvalene molecular clips for electron-deficient neutral guests through a straightforward Diels-Alder strategy
Hardouin-Lerouge, Marie,Cotelle, Yoann,Legoupy, Stphanie,Hudhomme, Pitrick
, p. 5341 - 5348 (2014)
An electroactive molecular clip incorporating tetrathiafulvalene (TTF) sidewalls grafted on a glycoluril platform has been synthesized using a straightforward Diels-Alder strategy. This way of attachment to the glycoluril U-shape scaffold afforded a rigidified and closed receptor for which the electron-rich TTF pincers are expected to be at a suitable distance for sandwiching neutral guests through donor-acceptor interactions. The efficient complexation ability of this host architecture toward one molecule of tetracyanoquinodimethane derivative (F4-TCNQ) in solution has been demonstrated using cyclic voltammetry and UV-Visible titration methods.
A novel dansyl-appended glycoluril-based fluorescence sensor for silver ions
Azam, Amir,Chawla,Pandey, Shubha
, p. 4710 - 4711 (2010)
Tetra-dansylated diphenyl glycoluril has been synthesized and evaluated for ionic recognition. The synthesized molecular receptor shows selective response to silver ions as determined through the enhancement of fluorescence intensity.
Glycoluril-tetrathiafulvalene molecular clips: On the influence of electronic and spatial properties for binding neutral accepting guests
Cotelle, Yoann,Hardouin-Lerouge, Marie,Legoupy, Stéphanie,Alévêque, Olivier,Levillain, Eric,Hudhomme, Piétrick
, p. 1023 - 1036 (2015/08/18)
Glycoluril-based molecular clips incorporating tetrathiafulvalene (TTF) sidewalls have been synthesized through different strategies with the aim of investigating the effect of electrochemical and spatial properties for binding neutral accepting guests. W
Synthesis and Binding Properties of Basked-Shaped Hosts
Smeets, Jan W. H.,Sijbesma, Rint P.,Dalen, Lydia van,Spek, Anthony L.,Smeets, Wilberth J. J.,Nolte, Roeland J. M.
, p. 3710 - 3717 (2007/10/02)
We described a novel, concave building block (4) for the synthesis of organic hosts.Compound 4 contains two fused 2-imidazolidone rings, which are flanked by two o-xylylene units.Basked-shaped hosts are constructed by attaching oxyethylene bridges to the