Bis(4-fluorophenyl)iodonium chloride

Base Information

• Chemical Name: Bis(4-fluorophenyl)iodonium chloride
• CAS No.: 1828-09-7
• Molecular Formula: C12H8 F2 I . Cl
• Molecular Weight: 352.55
• Hs Code.: 2903999090
• European Community (EC) Number: 217-376-9
• DSSTox Substance ID: DTXSID70939631
• Mol file: 1828-09-7.mol

Synonyms:1828-09-7;Bis(4-fluorophenyl)iodonium chloride;4,4'-Difluorodiphenyliodonium chloride;Bis(p-fluorophenyl)iodonium chloride;EINECS 217-376-9;Iodonium, bis(4-fluorophenyl)-, chloride;AI3-17463;IODONIUM, BIS(p-FLUOROPHENYL)-, CHLORIDE;bis(4-fluorophenyl)iodanium;chloride;4,4/'-DIFLUORODIPHENYLIODONIUM CHLORIDE;bis(4-fluorophenyl)iodanium chloride;Glycidyl4-toluenesulfonate;C12H8ClF2I;C12H8F2I.Cl;C12-H8-Cl-F2-I;SCHEMBL10849751;DTXSID70939631;bis-(4-Fluorophenyl)iodonium chloride;LS-84149;FT-0633868

Chemical Property of Bis(4-fluorophenyl)iodonium chloride

Chemical Property:

• PSA: 0.00000
• LogP: -2.90280
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 3
• Rotatable Bond Count: 2
• Exact Mass: 351.93273
• Heavy Atom Count: 16
• Complexity: 162

Purity/Quality:

98%,99%, ^*data from raw suppliers

4,4'-Difluorodiphenyliodonium chloride ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1=CC(=CC=C1F)[I+]C2=CC=C(C=C2)F.[Cl-]

Technology Process of Bis(4-fluorophenyl)iodonium chloride

There total 1 articles about Bis(4-fluorophenyl)iodonium chloride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

fluorobenzene (462-06-6) → bis-(4-fluoro-phenyl)-iodonium ; chloride (1828-09-7)

Guidance literature:

With iodyl sulfate; sulfuric acid;

DOI:10.1021/ja01511a020

Reference yield:

bis-(4-fluoro-phenyl)-iodonium ; chloride (1828-09-7) + C10H12I2O3 → C24H14I5O4(1+)*Cl(1-)

Guidance literature:

bis-(4-fluoro-phenyl)-iodonium ; chloride; C₁₀H₁₂I₂O₃; In N,N-dimethyl-formamide; at 23 ℃; for 0.5h;

With potassium carbonate; In N,N-dimethyl-formamide; at 90 ℃; for 3h;

With hydrogenchloride; In water; N,N-dimethyl-formamide; at 23 ℃; for 6h;

Reference yield:

4-ethoxyethoxyphenol (1140042-92-7) + bis-(4-fluoro-phenyl)-iodonium ; chloride (1828-09-7) → C24H18IO4(1+)*Cl(1-)

Guidance literature:

4-ethoxyethoxyphenol; bis-(4-fluoro-phenyl)-iodonium ; chloride; With sodium hydride; In tetrahydrofuran; at 5 - 23 ℃; for 3h;

With hydrogenchloride; In tetrahydrofuran; water; at 23 ℃; for 6h;

upstream raw materials:

fluorobenzene

Downstream raw materials:

3,3,3-Trifluoro-2-(4-fluoro-phenoxy)-2-trifluoromethyl-propionic acid ethyl ester

2-(4-fluorophenoxyimino)-2-(5-formamido-1,2,4-thiadiazol-3-yl)acetic acid

2-(4-fluorophenyl)-2-methyl-5-methoxy-6,7-dichloro-1-indanone