1'-(diphenylthiophosphoryl)ferrocenecarboxaldehyde

Base Information

Chemical Name:1'-(diphenylthiophosphoryl)ferrocenecarboxaldehyde
CAS No.:904690-32-0
Molecular Formula:C₂₃H₁₉FeOPS
Molecular Weight:430.29
Hs Code.:

Synonyms:1'-(diphenylthiophosphoryl)ferrocenecarboxaldehyde

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Chemical Property of 1'-(diphenylthiophosphoryl)ferrocenecarboxaldehyde

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Technology Process of 1'-(diphenylthiophosphoryl)ferrocenecarboxaldehyde

There total 1 articles about 1'-(diphenylthiophosphoryl)ferrocenecarboxaldehyde which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 89.0%

: 10544-50-0
sulfur

: 124944-40-7
1′-(diphenylphosphino)ferrocene-1-carbaldehyde

: 904690-32-0
1'-(diphenylthiophosphoryl)ferrocenecarboxaldehyde

Guidance literature:: In toluene; under Ar, with exclusion of direct day light; mixt. of Fe complex and S8in toluene gently refluxed for 1 h; filtered while hot; crystd. at -18°C; filtered; crystals washed with hexane; dried in air; second crop obtained by evapn. of mother liquor and crystn. from hot toluene; elem. anal.;
DOI:10.1016/j.jorganchem.2006.02.027

Reference yield: 88.0%

: 16940-66-2
sodium tetrahydroborate

: 904690-32-0
1'-(diphenylthiophosphoryl)ferrocenecarboxaldehyde

: 954149-64-5
[1'-(diphenylthiophosphanyl)ferrocen-1-yl]methanol

Guidance literature:: With sodium hydroxide; In toluene; Fe compd. treated with borate at 0°C (toluene/NaOH);
DOI:10.1002/ejic.200601193

Reference yield: 83.0%

: 558-13-4
carbon tetrabromide

: 904690-32-0
1'-(diphenylthiophosphoryl)ferrocenecarboxaldehyde

: 904690-33-1
1'-(diphenylthiophosphoryl)-1-(2,2-dibromovinyl)ferrocene

Guidance literature:: With PPh₃; NaHCO₃; H₂O₂; In dichloromethane; under Ar, with exclusion of direct day light; soln. of CBr4 in CH2Cl2 introduced slowly to ice cooled soln. of Fe complex and PPh3 in dry CH2Cl2with stirring; stirred (0°C, 20 min); satd. aq. NaHCO3 and 30% H 2O2 added; stirred for 15 min; org. layer washed (aq. Na2S2O3); dried (MgSO4); mixed with alumina; evapd.; chromd. (alumina, Et2O); evapd. to dryness; taken up in CHCl3; evapd.; hot MeOH added; stored at 0°C overnight; filtered; washed (MeOH); dried under vac.; elem. anal.;
DOI:10.1016/j.jorganchem.2006.02.027