Technology Process of 4-methyl-N-(2-methylallyl)-N-(p-tolyl)aniline
There total 1 articles about 4-methyl-N-(2-methylallyl)-N-(p-tolyl)aniline which
guide to synthetic route it.
The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:
synthetic route:
- Guidance literature:
-
di-p-tolylamine;
With
sodium hydride;
In
tetrahydrofuran; mineral oil;
for 0.5h;
Inert atmosphere;
2-methyl-3-bromo-1-propene;
With
potassium iodide;
In
tetrahydrofuran; mineral oil;
for 5h;
Inert atmosphere;
Reflux;
DOI:10.1002/anie.201200431
- Guidance literature:
-
With
potassium osmate(VI) dihydrate; 4-methylmorpholine N-oxide;
In
tetrahydrofuran; water; acetone;
at 20 ℃;
for 28h;
pH=7;
Inert atmosphere;
aq. buffer;
DOI:10.1002/anie.201200431
- Guidance literature:
-
Multi-step reaction with 3 steps
1.1: potassium osmate(VI) dihydrate; 4-methylmorpholine N-oxide / tetrahydrofuran; water; acetone / 28 h / 20 °C / pH 7 / Inert atmosphere; aq. buffer
2.1: sodium hydride / tetrahydrofuran; mineral oil / 0.5 h / Inert atmosphere
2.2: 20 h / 20 °C / Inert atmosphere
3.1: manganese; bis(cyclopentadienyl)titanium dichloride; 2,4,6-collidine hydrochloride / tetrahydrofuran / 2 h / 95 °C / Inert atmosphere
With
bis(cyclopentadienyl)titanium dichloride; potassium osmate(VI) dihydrate; manganese; 2,4,6-collidine hydrochloride; sodium hydride; 4-methylmorpholine N-oxide;
In
tetrahydrofuran; water; acetone; mineral oil;
DOI:10.1002/anie.201200431
