(R)-4-methyl-4-phenyl-2-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-1,5-hexadiene

Base Information

Chemical Name:(R)-4-methyl-4-phenyl-2-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-1,5-hexadiene
CAS No.:1426250-31-8
Molecular Formula:C₁₉H₂₇BO₂
Molecular Weight:298.233
Hs Code.:

Synonyms:(R)-4-methyl-4-phenyl-2-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-1,5-hexadiene

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Chemical Property of (R)-4-methyl-4-phenyl-2-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-1,5-hexadiene

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Technology Process of (R)-4-methyl-4-phenyl-2-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-1,5-hexadiene

There total 2 articles about (R)-4-methyl-4-phenyl-2-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-1,5-hexadiene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 92.0%

: 1353901-52-6
(R)-3-methyl-3-phenyl-1,4,5-hexatriene

: 73183-34-3
bis(pinacol)diborane

: 1426250-31-8
(R)-4-methyl-4-phenyl-2-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-1,5-hexadiene

Guidance literature:: bis(pinacol)diborane; With copper(l) chloride; sodium t-butanolate; 1,3-bis[2,6-diisopropylphenyl]imidazolium chloride; In tetrahydrofuran; at 22 ℃; for 0.5h; Inert atmosphere;

(R)-3-methyl-3-phenyl-1,4,5-hexatriene; With methanol; In tetrahydrofuran; at 22 ℃; for 8h; stereoselective reaction; Inert atmosphere;
DOI:10.1021/ol4004178

Reference yield: 44.0%

: 124604-57-5
[(1E)-3-chloro-1-methylprop-1-en-1-yl]benzene

: C₁₅H₂₈B₂O₄

: 1426250-31-8
(R)-4-methyl-4-phenyl-2-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-1,5-hexadiene

Guidance literature:: With (R)-(+)-2,2′-bis(di-2-furanylphosphino)-6,6′-dimethoxy-1,1′-biphenyl; bis(η3-allyl-μ-chloropalladium(II)); cesium fluoride; In tetrahydrofuran; water; at 60 ℃; for 24h; enantioselective reaction; Inert atmosphere;
DOI:10.1021/ol400088g

Reference yield:

: 1426250-31-8
(R)-4-methyl-4-phenyl-2-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-1,5-hexadiene

: 1427549-48-1
C₁₃H₁₆O

Guidance literature:: With dihydrogen peroxide; sodium hydroxide; In tetrahydrofuran; at 0 - 23 ℃; for 4h; Inert atmosphere;
DOI:10.1021/ol400088g