Diethyl 2-bromo-2-methylmalonate

Base Information

Chemical Name:Diethyl 2-bromo-2-methylmalonate
CAS No.:29263-94-3
Molecular Formula:C8H13BrO4
Molecular Weight:253.093
Hs Code.:2917190090
European Community (EC) Number:249-541-6
NSC Number:10117
DSSTox Substance ID:DTXSID90183518
Nikkaji Number:J591.349G
Wikidata:Q72469213
Mol file:29263-94-3.mol

Synonyms:Diethyl 2-bromo-2-methylmalonate;29263-94-3;Diethyl bromomethylmalonate;diethyl 2-bromo-2-methylpropanedioate;2-bromo-2-methylmalonic acid diethyl ester;Propanedioic acid, 2-bromo-2-methyl-, 1,3-diethyl ester;Diethyl methylbromomalonate;C8H13BrO4;Diethyl2-bromo-2-methylmalonate;diethyl-2-bromo-2-methyl malonate;EINECS 249-541-6;1,3-diethyl 2-bromo-2-methylpropanedioate;2-Bromo-2-methylpropandioic acid diethyl ester;SCHEMBL653853;CSLQAXTUGPUBCW-UHFFFAOYSA-;DTXSID90183518;diethyl-2-bromo-2-methyl-malonate;NSC10117;MFCD00009125;NSC 10117;NSC-10117;AKOS015900374;CS-W001079;Diethyl 2-bromo-2-methylmalonate, 98%;Malonic acid, bromomethyl-, diethyl ester;2-bromo-2-methyl-malonic acid diethyl ester;D4368;FT-0611396;FT-0624770;2-(bromomethyl)-propanedioic acid diethyl ester;EN300-243691;Propanedioic acid, bromomethyl-, diethyl ester;A819852;W-106996;F0001-0911;diethyl 2-bromo-2-methyl-propanedioate;Diethyl 2-Bromo-2-methylmalonate

Suppliers and Price of Diethyl 2-bromo-2-methylmalonate

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

TCI Chemical
Diethyl 2-Bromo-2-methylmalonate >98.0%(GC)(T)
25g
$ 104.00

Sigma-Aldrich
Diethyl 2-bromo-2-methylmalonate 98%
25g
$ 95.50

Biosynth Carbosynth
Diethyl 2-bromo-2-methylmalonate
25 g
$ 195.50

Biosynth Carbosynth
Diethyl 2-bromo-2-methylmalonate
10 g
$ 120.00

Biosynth Carbosynth
Diethyl 2-bromo-2-methylmalonate
250 g
$ 800.00

Biosynth Carbosynth
Diethyl 2-bromo-2-methylmalonate
100 g
$ 560.00

Biosynth Carbosynth
Diethyl 2-bromo-2-methylmalonate
50 g
$ 325.00

American Custom Chemicals Corporation
DIETHYL 2-BROMO-2-METHYLMALONATE 95.00%
25G
$ 1150.05

Ambeed
Diethyl 2-Bromo-2-methylmalonate 98%
25g
$ 37.00

Ambeed
Diethyl 2-Bromo-2-methylmalonate 98%
10g
$ 17.00

Total 56 raw suppliers

Chemical Property of Diethyl 2-bromo-2-methylmalonate

Chemical Property:

Appearance/Colour:clear, colorless liquid
Vapor Pressure:0.0433mmHg at 25°C
Refractive Index:n20/D 1.449(lit.)
Boiling Point:238.04 °C at 760 mmHg
Flash Point:97.764 °C
PSA：52.60000
Density:1.4 g/cm³
LogP:1.26620
Storage Temp.:Inert atmosphere,Room Temperature
XLogP3:2
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:4
Rotatable Bond Count:6
Exact Mass:251.99972
Heavy Atom Count:13
Complexity:184

Purity/Quality:

99% GC ^*data from raw suppliers

Diethyl 2-Bromo-2-methylmalonate >98.0%(GC)(T) ^*data from reagent suppliers

Safty Information:

Pictogram(s): C
Hazard Codes:C
Statements: 34-20/21/22
Safety Statements: 26-36/37/39-45

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CCOC(=O)C(C)(C(=O)OCC)Br
Uses Diethyl 2-bromo-2-methylmalonate was used to investigate the 1,2,2,6,6-pentamethylpiperidine as an effective reducing agent for the radical chain conversion of primary bromoesters to the corresponding esters. It was used in the synthesis of polystyrene macroinitiator via atom transfer radical polymerization.

Technology Process of Diethyl 2-bromo-2-methylmalonate

There total 2 articles about Diethyl 2-bromo-2-methylmalonate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

: 609-08-5
Diethyl methylmalonate

: 29263-94-3
diethyl bromomethylmalonate

Guidance literature:: With aluminum oxide; copper(ll) bromide; In acetonitrile; at 50 ℃; for 1h;
DOI:10.1246/cl.1998.1091

Reference yield:

: 29263-94-3
diethyl bromomethylmalonate

Guidance literature:: DOI:10.1021/ja00760a086

Reference yield: 97.0%

: 637-69-4,24936-44-5
4-Methoxystyrene

: 27816-53-1
1,5-dimethyl-1H-indole

: 29263-94-3
diethyl bromomethylmalonate

: diethyl 2-(2-(1,5-dimethyl-1H-indol-3-yl)-2-(4-methoxyphenyl)-ethyl)-2-methylmalonate

Guidance literature:: With iron(III)-acetylacetonate; silver carbonate; In 1,4-dioxane; at 120 ℃; for 12h; Inert atmosphere;
DOI:10.1002/anie.201511624