(1SR,6RS,7RS)-4-benzylidine-7-((tert-butyldimethylsilyl)oxy)-1,6-dimethylbicyclo<4.4.0>decan-3-one

Base Information

Chemical Name:(1SR,6RS,7RS)-4-benzylidine-7-((tert-butyldimethylsilyl)oxy)-1,6-dimethylbicyclo<4.4.0>decan-3-one
CAS No.:80800-71-1
Molecular Formula:C₂₅H₃₈O₂Si
Molecular Weight:398.661
Hs Code.:

Synonyms:(1SR,6RS,7RS)-4-benzylidine-7-((tert-butyldimethylsilyl)oxy)-1,6-dimethylbicyclo<4.4.0>decan-3-one

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of (1SR,6RS,7RS)-4-benzylidine-7-((tert-butyldimethylsilyl)oxy)-1,6-dimethylbicyclo<4.4.0>decan-3-one

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Technology Process of (1SR,6RS,7RS)-4-benzylidine-7-((tert-butyldimethylsilyl)oxy)-1,6-dimethylbicyclo<4.4.0>decan-3-one

There total 3 articles about (1SR,6RS,7RS)-4-benzylidine-7-((tert-butyldimethylsilyl)oxy)-1,6-dimethylbicyclo<4.4.0>decan-3-one which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 20007-99-2,33878-99-8,100348-93-4,20007-72-1
Wieland-Miescher ketone

: 80800-71-1
(1SR,6RS,7RS)-4-benzylidine-7-((tert-butyldimethylsilyl)oxy)-1,6-dimethylbicyclo<4.4.0>decan-3-one

Guidance literature:: Multi-step reaction with 3 steps

1: NaBH₄ / propan-2-ol

2: imidazole / dimethylformamide

3: 2.) NaOH / 1.) Et₂O, room temperature, 1 h, 2.) EtOH, 40 h

With 1H-imidazole; sodium hydroxide; sodium tetrahydroborate; In N,N-dimethyl-formamide; isopropyl alcohol;
DOI:10.1021/ja00371a020

Reference yield:

: 50302-16-4
(4aS,5S)-5-Hydroxy-4a-methyl-4,4a,5,6,7,8-hexahydro-3H-naphthalen-2-one

: 80800-71-1
(1SR,6RS,7RS)-4-benzylidine-7-((tert-butyldimethylsilyl)oxy)-1,6-dimethylbicyclo<4.4.0>decan-3-one

Guidance literature:: Multi-step reaction with 2 steps

1: imidazole / dimethylformamide

2: 2.) NaOH / 1.) Et₂O, room temperature, 1 h, 2.) EtOH, 40 h

With 1H-imidazole; sodium hydroxide; In N,N-dimethyl-formamide;
DOI:10.1021/ja00371a020

Reference yield:

: 15681-48-8
lithium dimethylcuprate

: 100-52-7
benzaldehyde

: 80800-69-7
(8S^*, 8aS^*)-8-tert-butyldimethylsilyloxy-8a-methyl-1,5,6,7,8,8a-hexahydronaphthalen-3(2H)-one

: 80800-71-1
(1SR,6RS,7RS)-4-benzylidine-7-((tert-butyldimethylsilyl)oxy)-1,6-dimethylbicyclo<4.4.0>decan-3-one

Guidance literature:: With sodium hydroxide; Yield given. Multistep reaction; 1.) Et₂O, room temperature, 1 h, 2.) EtOH, 40 h;
DOI:10.1021/ja00371a020