Technology Process of C23H34Cl3NO5Si
There total 14 articles about C23H34Cl3NO5Si which
guide to synthetic route it.
The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:
synthetic route:
- Guidance literature:
-
With
sodium carbonate;
In
tert-butylbenzene;
at 170 ℃;
for 24h;
optical yield given as %de;
DOI:10.1002/asia.201000602
- Guidance literature:
-
Multi-step reaction with 3 steps
1: diisobutylaluminium hydride / toluene / 0.5 h / -78 °C
2: dichloromethane / 1 h / 0 °C
3: sodium carbonate / tert-butylbenzene / 24 h / 170 °C
With
diisobutylaluminium hydride; sodium carbonate;
In
tert-butylbenzene; dichloromethane; toluene;
3: Overman rearrangement;
DOI:10.1002/asia.201000602
- Guidance literature:
-
Multi-step reaction with 9 steps
1.1: acetic anhydride; dimethyl sulfoxide / 2 h / 50 °C
2.1: toluene / 4 h / -40 °C
3.1: magnesium / methanol / 2 h / 20 °C
4.1: sulfur trioxide pyridine complex; dimethyl sulfoxide; triethylamine / 4 h / 20 °C
5.1: sodium hydride / tetrahydrofuran; hexane; mineral oil / 0.17 h / 0 °C
5.2: 0 - 20 °C
6.1: pyridine / dichloromethane / 2 h / 0 °C
7.1: diisobutylaluminium hydride / toluene / 0.5 h / -78 °C
8.1: dichloromethane / 1 h / 0 °C
9.1: sodium carbonate / tert-butylbenzene / 24 h / 170 °C
With
pyridine; sulfur trioxide pyridine complex; acetic anhydride; sodium hydride; diisobutylaluminium hydride; sodium carbonate; magnesium; dimethyl sulfoxide; triethylamine;
In
tetrahydrofuran; methanol; tert-butylbenzene; hexane; dichloromethane; toluene; mineral oil;
4.1: Swern oxidation / 5.2: Horner-Wadsworth-Emmons olefination / 9.1: Overman rearrangement;
DOI:10.1002/asia.201000602
