tert-Butyl-[2-[(E)-(S)-1-phenyl-ethylimino]-eth-(E)-ylidene]-amine

Base Information

• Chemical Name: tert-Butyl-[2-[(E)-(S)-1-phenyl-ethylimino]-eth-(E)-ylidene]-amine
• CAS No.: 484066-16-2
• Molecular Formula: C₁₄H₂₀N₂
• Molecular Weight: 216.326
• Mol file: 484066-16-2.mol

Synonyms:tert-Butyl-[2-[(E)-(S)-1-phenyl-ethylimino]-eth-(E)-ylidene]-amine

Chemical Property of tert-Butyl-[2-[(E)-(S)-1-phenyl-ethylimino]-eth-(E)-ylidene]-amine

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of tert-Butyl-[2-[(E)-(S)-1-phenyl-ethylimino]-eth-(E)-ylidene]-amine

There total 1 articles about tert-Butyl-[2-[(E)-(S)-1-phenyl-ethylimino]-eth-(E)-ylidene]-amine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 43.0%

Glyoxal (131543-46-9,107-22-2) + (S)-1-phenyl-ethylamine (2627-86-3) + tert-butylamine (75-64-9) → tert-Butyl-[2-[(E)-(S)-1-phenyl-ethylimino]-eth-(E)-ylidene]-amine (484066-16-2)

Guidance literature:

In hexane; water; at 20 ℃; for 0.5h;

DOI:10.1002/1099-0682(200209)2002:9<2438::AID-EJIC2438>3.0.CO;2-W

Reference yield: 90.0%

tert-Butyl-[2-[(E)-(S)-1-phenyl-ethylimino]-eth-(E)-ylidene]-amine (484066-16-2) → (S)-[Me3CN(a)CHCHN(b)(CH(Ph)Me)BBr2]Br(N(a)-B)

Guidance literature:

With boron tribromide; In hexane; at 20 ℃; for 0.5h;

DOI:10.1002/1099-0682(200209)2002:9<2438::AID-EJIC2438>3.0.CO;2-W

Reference yield:

tert-Butyl-[2-[(E)-(S)-1-phenyl-ethylimino]-eth-(E)-ylidene]-amine (484066-16-2) → (S)-Me3CN(a)CHCHN(b)[CH(Ph)Me]BCN(N(a)-B)

Guidance literature:

Multi-step reaction with 4 steps

1: 90 percent / BBr₃ / hexane / 0.5 h / 20 °C

2: 66 percent / Na/Hg / hexane / 48 h

3: acetonitrile; hexane / 1 h

4: Heating

With sodium amalgam; boron tribromide; In hexane; acetonitrile;

DOI:10.1002/1099-0682(200209)2002:9<2438::AID-EJIC2438>3.0.CO;2-W

upstream raw materials:

Glyoxal

(S)-1-phenyl-ethylamine

tert-butylamine

Downstream raw materials:

(S)-Me₃CN(a)CHCHN(b)[CH(Ph)Me]BBr(N(a)-B)

(S)-Me₃CN(a)CHCHN(b)[CH(Ph)Me]B-NC(N(a)-B)