LITHIUM NITRIDE

Base Information

• Chemical Name: LITHIUM NITRIDE
• CAS No.: 26134-62-3
• Molecular Formula: Li3N
• Molecular Weight: 34.82
• Mol file: 26134-62-3.mol

Synonyms:Lithiumnitride;Trilithium nitride;Trilithium nitride (Li3N);

Chemical Property of LITHIUM NITRIDE

Chemical Property:

• Appearance/Colour: fine red-brown powder
• Melting Point: 845°C
• Boiling Point: °Cat760mmHg
• Flash Point: °C
• PSA: 3.24000
• Density: 1.3 g/mL at 25 °C(lit.)
• LogP: -0.31870
• Sensitive.: Moisture Sensitive
• Solubility.: Insoluble in organic solvents.
• Water Solubility.: reacts with H2O, yielding LiOH and ammonia; insoluble polyethers [HAW93]

Purity/Quality:

99.9% ^*data from raw suppliers

Lithium nitride (99.5%-Li) ^*data from reagent suppliers

Safty Information:

• Pictogram(s): Ignites in air, use dry chemicals to extinguish (“Lith-X.”)
• Hazard Codes: F,C
• Statements: 11-14-29-34-14/15
• Safety Statements: 16-22-26-27-36/37/39-45

MSDS Files:

SDS file from LookChem

Useful:

• Uses: Lithium nitride is used in metallurgy and chemical synthesis. It is also used to store hydrogen and acts as a source of the nitride ion. It is involved in the preparation of lithium hydride and lithium amide as well as a reducing agent.

Refernces

Reaction of oxygen difluoride with sulfur dioxide, sulfur trioxide, and peroxydisulfuryl difluoride

10.1021/ic50016a044

The main content of the study revolves around the chemical reactions involving various nitrides and oxygen difluoride (O2F2). The research explores the fluorination of different types of nitrides, such as lithium nitride (Li3N), beryllium nitride (Be3N2), magnesium nitride (Mg3N2), boron nitride (BN), silicon nitride (Si3N4), titanium nitride (TiN), vanadium nitride (VN), and copper(I) nitride, using elementary fluorine. The aim is to establish if there is a relationship between the structure of a nitride and the formation of nitrogen trifluoride (NF3) as a product of its direct fluorination. Additionally, the study investigates the reaction of oxygen difluoride with sulfur dioxide, sulfur trioxide, and peroxydisulfuryl difluoride, focusing on the photochemical decomposition and the role of 0-F radical species as reaction intermediates. The experiments involve irradiating gaseous mixtures with ultraviolet light to observe the reactions and identify the products, which include peroxysulfuryl difluoride, pyrosulfuryl fluoride, sulfuryl fluoride, and fluorine fluorosulfonate, among others. The study employs various analytical techniques such as infrared and F19 n.m.r. spectroscopy to characterize the compounds formed.

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