1-(Trifluoromethoxy)-4-vinylbenzene

Base Information

Chemical Name:1-(Trifluoromethoxy)-4-vinylbenzene
CAS No.:1736-08-9
Molecular Formula:C₉H₇F₃O
Molecular Weight:188.149
Hs Code.:
European Community (EC) Number:850-710-7
DSSTox Substance ID:DTXSID901288597
Nikkaji Number:J3.242.526G

Synonyms:1-(trifluoromethoxy)-4-vinylbenzene;1736-08-9;4-(Trifluoromethoxy)styrene;1-ethenyl-4-(trifluoromethoxy)benzene;4-ethenylphenyl trifluoromethyl ether;SCHEMBL171790;SCHEMBL13158947;VMSMGVZQOQFMKN-UHFFFAOYSA-N;DTXSID901288597;BAA73608;MFCD22413864;AKOS018695870;AS-44152;CS-0105967;EN300-220001;A1-09622

Suppliers and Price of 1-(Trifluoromethoxy)-4-vinylbenzene

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 6 raw suppliers

Chemical Property of 1-(Trifluoromethoxy)-4-vinylbenzene

Chemical Property:

XLogP3:3.9
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:4
Rotatable Bond Count:2
Exact Mass:188.04489933
Heavy Atom Count:13
Complexity:168

Purity/Quality:: 97% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Canonical SMILES:C=CC1=CC=C(C=C1)OC(F)(F)F

Technology Process of 1-(Trifluoromethoxy)-4-vinylbenzene

There total 5 articles about 1-(Trifluoromethoxy)-4-vinylbenzene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 68.0%

: 108-05-4,9003-20-7
vinyl acetate

: 407-14-7
1-bromo-4-(trifluoromethoxy)benzene

: 1736-08-9
4-ethenylphenyl trifluoromethyl ether

Guidance literature:: With 1,3-bis[(diphenylphosphino)propane]dichloronickel(II); lithium iodide; zinc; at 65 ℃; for 8h; Inert atmosphere; Sealed tube; Green chemistry;
DOI:10.1021/acs.orglett.1c04018

Reference yield: 60.0%

: 407-14-7
1-bromo-4-(trifluoromethoxy)benzene

: 7486-35-3
tri-n-butyl(vinyl)tin

: 1736-08-9
4-ethenylphenyl trifluoromethyl ether

Guidance literature:: With tetrakis(triphenylphosphine) palladium⁽⁰⁾; In N,N-dimethyl-formamide; for 48h; Inert atmosphere; Reflux;
DOI:10.1016/j.tet.2012.09.036

Reference yield: 25.0%

: 659-28-9
p-trifluoromethoxybenzaldehyde

: 1779-49-3
Methyltriphenylphosphonium bromide

: 1736-08-9
4-ethenylphenyl trifluoromethyl ether

Guidance literature:: Methyltriphenylphosphonium bromide; With n-butyllithium; In tetrahydrofuran; at -78 - 20 ℃; for 1h; Inert atmosphere;

p-trifluoromethoxybenzaldehyde; In tetrahydrofuran; at 20 ℃; for 16h; Inert atmosphere;