phenyl[(2S)-3-[(tert-butyldiphenylsilyl)oxy]-2-methylpropan-1-yl]sulfide

Base Information

Chemical Name:phenyl[(2S)-3-[(tert-butyldiphenylsilyl)oxy]-2-methylpropan-1-yl]sulfide
CAS No.:366454-91-3
Molecular Formula:C₂₆H₃₂OSSi
Molecular Weight:420.691
Hs Code.:

Synonyms:phenyl[(2S)-3-[(tert-butyldiphenylsilyl)oxy]-2-methylpropan-1-yl]sulfide

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Chemical Property of phenyl[(2S)-3-[(tert-butyldiphenylsilyl)oxy]-2-methylpropan-1-yl]sulfide

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Technology Process of phenyl[(2S)-3-[(tert-butyldiphenylsilyl)oxy]-2-methylpropan-1-yl]sulfide

There total 8 articles about phenyl[(2S)-3-[(tert-butyldiphenylsilyl)oxy]-2-methylpropan-1-yl]sulfide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

: 143088-61-3
(2S)-1-bromo-3-[(tert-butyldiphenylsilyl)oxy]-2-methylpropane

: 108-98-5
thiophenol

: 366454-91-3
phenyl[(2S)-3-[(tert-butyldiphenylsilyl)oxy]-2-methylpropan-1-yl]sulfide

Guidance literature:: thiophenol; With sodium hydroxide; In methanol; at 20 ℃; for 0.416667h;

(2S)-1-bromo-3-[(tert-butyldiphenylsilyl)oxy]-2-methylpropane; In tetrahydrofuran; methanol; for 22h; Further stages.;
DOI:10.1021/ja011256n

Reference yield: 95.0%

: 121783-49-1
(S)-(+)-2-methyl-3-(phenylthio)propan-1-ol

: 58479-61-1
tert-butylchlorodiphenylsilane

: 366454-91-3
phenyl[(2S)-3-[(tert-butyldiphenylsilyl)oxy]-2-methylpropan-1-yl]sulfide

Guidance literature:: With 1H-imidazole; In dichloromethane; at 0 - 20 ℃; for 1h;
DOI:10.1039/c5ob01750e

Reference yield:

: 58479-61-1
tert-butylchlorodiphenylsilane

: 366454-91-3
phenyl[(2S)-3-[(tert-butyldiphenylsilyl)oxy]-2-methylpropan-1-yl]sulfide

Guidance literature:: Multi-step reaction with 3 steps

1: imidazole / dimethylformamide / 4 h

2: CaCl₂; NaBH₄ / tetrahydrofuran; diethyl ether / 0 - 20 °C

3: n-Bu₃P / benzene / 2.5 h / 20 °C

With 1H-imidazole; sodium tetrahydroborate; tributylphosphine; calcium chloride; In tetrahydrofuran; diethyl ether; N,N-dimethyl-formamide; benzene;
DOI:10.1021/jo0503862