(2E,4Z)-methyl 6-((4E,6E)-N-(4-methoxybenzyl)-6,8-dimethyl-3-oxonona-4,6-dienamido)-5-methylhexa-2,4-dienoate

Base Information

Chemical Name:(2E,4Z)-methyl 6-((4E,6E)-N-(4-methoxybenzyl)-6,8-dimethyl-3-oxonona-4,6-dienamido)-5-methylhexa-2,4-dienoate
CAS No.:1443224-00-7
Molecular Formula:C₂₇H₃₅NO₅
Molecular Weight:453.579
Hs Code.:

Synonyms:(2E,4Z)-methyl 6-((4E,6E)-N-(4-methoxybenzyl)-6,8-dimethyl-3-oxonona-4,6-dienamido)-5-methylhexa-2,4-dienoate

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Chemical Property of (2E,4Z)-methyl 6-((4E,6E)-N-(4-methoxybenzyl)-6,8-dimethyl-3-oxonona-4,6-dienamido)-5-methylhexa-2,4-dienoate

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Technology Process of (2E,4Z)-methyl 6-((4E,6E)-N-(4-methoxybenzyl)-6,8-dimethyl-3-oxonona-4,6-dienamido)-5-methylhexa-2,4-dienoate

There total 4 articles about (2E,4Z)-methyl 6-((4E,6E)-N-(4-methoxybenzyl)-6,8-dimethyl-3-oxonona-4,6-dienamido)-5-methylhexa-2,4-dienoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 81.0%

: 1443224-09-6
(4E,6E)-N-(4-methoxybenzyl)-6,8-dimethyl-N-((Z)-2-methylpenta-2,4-dien-1-yl)-3-oxonona-4,6-dienamide

: 292638-85-8,9003-21-8,96-33-3
acrylic acid methyl ester

: 1443224-00-7
(2E,4Z)-methyl 6-((4E,6E)-N-(4-methoxybenzyl)-6,8-dimethyl-3-oxonona-4,6-dienamido)-5-methylhexa-2,4-dienoate

Guidance literature:: With Hoveyda-Grubbs catalyst second generation; In dichloromethane; at 45 ℃; for 3h; Inert atmosphere;
DOI:10.1021/ol401354a

Reference yield:

: 67065-88-7
(Z)-2-methylpenta-2,4-dien-1-ol

: 1443224-00-7
(2E,4Z)-methyl 6-((4E,6E)-N-(4-methoxybenzyl)-6,8-dimethyl-3-oxonona-4,6-dienamido)-5-methylhexa-2,4-dienoate

Guidance literature:: Multi-step reaction with 4 steps

1: N-Bromosuccinimide; triphenylphosphine / tetrahydrofuran / 0.33 h / -10 °C / Inert atmosphere

2: tetrahydrofuran / 12 h / -10 - 23 °C / Inert atmosphere

3: pyridinium p-toluenesulfonate / toluene / 3 h / 110 °C / Inert atmosphere

4: Hoveyda-Grubbs catalyst second generation / dichloromethane / 3 h / 45 °C / Inert atmosphere

With N-Bromosuccinimide; Hoveyda-Grubbs catalyst second generation; pyridinium p-toluenesulfonate; triphenylphosphine; In tetrahydrofuran; dichloromethane; toluene;
DOI:10.1021/ol401354a

Reference yield:

: (Z)-N-(4-methoxybenzyl)-2-methylpenta-2,4-dien-1-amine

: 1443224-00-7
(2E,4Z)-methyl 6-((4E,6E)-N-(4-methoxybenzyl)-6,8-dimethyl-3-oxonona-4,6-dienamido)-5-methylhexa-2,4-dienoate

Guidance literature:: Multi-step reaction with 2 steps

1: pyridinium p-toluenesulfonate / toluene / 3 h / 110 °C / Inert atmosphere

2: Hoveyda-Grubbs catalyst second generation / dichloromethane / 3 h / 45 °C / Inert atmosphere

With Hoveyda-Grubbs catalyst second generation; pyridinium p-toluenesulfonate; In dichloromethane; toluene;
DOI:10.1021/ol401354a