methyl (3S,4R,5S,6Z,9R)-3-benzyloxy-4-hydroxy-5-trimethylsilyl-9-{[2-(trimethylsilyl)ethoxy]methoxy}dec-6-enoate

Base Information

Chemical Name:methyl (3S,4R,5S,6Z,9R)-3-benzyloxy-4-hydroxy-5-trimethylsilyl-9-{[2-(trimethylsilyl)ethoxy]methoxy}dec-6-enoate
CAS No.:1237524-92-3
Molecular Formula:C₂₇H₄₈O₆Si₂
Molecular Weight:524.846
Hs Code.:

Synonyms:methyl (3S,4R,5S,6Z,9R)-3-benzyloxy-4-hydroxy-5-trimethylsilyl-9-{[2-(trimethylsilyl)ethoxy]methoxy}dec-6-enoate

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Chemical Property of methyl (3S,4R,5S,6Z,9R)-3-benzyloxy-4-hydroxy-5-trimethylsilyl-9-{[2-(trimethylsilyl)ethoxy]methoxy}dec-6-enoate

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Technology Process of methyl (3S,4R,5S,6Z,9R)-3-benzyloxy-4-hydroxy-5-trimethylsilyl-9-{[2-(trimethylsilyl)ethoxy]methoxy}dec-6-enoate

There total 1 articles about methyl (3S,4R,5S,6Z,9R)-3-benzyloxy-4-hydroxy-5-trimethylsilyl-9-{[2-(trimethylsilyl)ethoxy]methoxy}dec-6-enoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 85.0%

: (E)-Me₃Si-=-B-9BBN

: (1R,3R)-1-(tributylstannyl)-3-{[2-(trimethylsilyl)ethoxy]methoxy}butyl diisopropylcarbamate

: 129151-77-5
(S)-methyl 3-(benzyloxy)-4-oxobutanoate

: 1237524-92-3
methyl (3S,4R,5S,6Z,9R)-3-benzyloxy-4-hydroxy-5-trimethylsilyl-9-{[2-(trimethylsilyl)ethoxy]methoxy}dec-6-enoate

Guidance literature:: (1R,3R)-1-(tributylstannyl)-3-{[2-(trimethylsilyl)ethoxy]methoxy}butyl diisopropylcarbamate; With n-butyllithium; In diethyl ether; hexane; at -78 ℃; for 1h; Inert atmosphere;

(E)-Me₃Si-=-B-9BBN; In diethyl ether; hexane; at -78 ℃; for 0.25h; Inert atmosphere;

(S)-methyl 3-(benzyloxy)-4-oxobutanoate; stereoselective reaction;
DOI:10.1002/anie.201001223

Reference yield:

: 1237524-92-3
methyl (3S,4R,5S,6Z,9R)-3-benzyloxy-4-hydroxy-5-trimethylsilyl-9-{[2-(trimethylsilyl)ethoxy]methoxy}dec-6-enoate

: C₂₇H₄₈O₇Si₂

Guidance literature:: With sodium hydrogencarbonate; 3-chloro-benzenecarboperoxoic acid; In dichloromethane; at -20 ℃; for 4h;
DOI:10.1002/anie.201001223