(2S,3R)-(+)-methyl 2-benzyl-3-[(S)-(4-methylphenylsulfinamido)]-3-pent-4-enonate

Base Information

Chemical Name:(2S,3R)-(+)-methyl 2-benzyl-3-[(S)-(4-methylphenylsulfinamido)]-3-pent-4-enonate
CAS No.:1287731-56-9
Molecular Formula:C₂₀H₂₃NO₃S
Molecular Weight:357.474
Hs Code.:

Synonyms:(2S,3R)-(+)-methyl 2-benzyl-3-[(S)-(4-methylphenylsulfinamido)]-3-pent-4-enonate

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of (2S,3R)-(+)-methyl 2-benzyl-3-[(S)-(4-methylphenylsulfinamido)]-3-pent-4-enonate

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Technology Process of (2S,3R)-(+)-methyl 2-benzyl-3-[(S)-(4-methylphenylsulfinamido)]-3-pent-4-enonate

There total 1 articles about (2S,3R)-(+)-methyl 2-benzyl-3-[(S)-(4-methylphenylsulfinamido)]-3-pent-4-enonate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 82.0%

: 620-05-3
iodomethylbenzene

: 667457-50-3
(S_S,R)-(+)-methyl 3-(p-toluenesulfinylamino)-pent-4-enoate

: 1287731-56-9
(2S,3R)-(+)-methyl 2-benzyl-3-[(S)-(4-methylphenylsulfinamido)]-3-pent-4-enonate

Guidance literature:: (S_S,R)-(+)-methyl 3-(p-toluenesulfinylamino)-pent-4-enoate; With n-butyllithium; diisopropylamine; lithium chloride; In tetrahydrofuran; hexane; at -78 ℃; for 1h; Inert atmosphere;

iodomethylbenzene; In tetrahydrofuran; hexane; tert-butyl methyl ether; at -50 ℃; optical yield given as %de; diastereoselective reaction; Inert atmosphere;
DOI:10.1021/jo2002352