667457-50-3

Upstream product

• 79-20-9 acetic acid methyl ester 
• 188447-83-8 (S)-(+)-N-(prop-2-enylidene)-p-toluenesulfinamide 

Downstream Products

• 667457-51-4 (S_S,R)-(+)-dimethyl [2-oxo-4-(p-toluenesulfinylamino)-hex-5-enyl]-phosphonate 
• 1287731-55-8 (2S,3R)-(+)-methyl 2-(2-propenyl)-3-[(S)-(4-methylphenylsulfinamido)]-3-pent-4-enonate 
• 1287731-56-9 (2S,3R)-(+)-methyl 2-benzyl-3-[(S)-(4-methylphenylsulfinamido)]-3-pent-4-enonate 
• 1287731-60-5 (2S,3S)-(+)-N-methoxy-N-methyl-2-(2-propenyl)-3-[(S)-(4-methylphenylsulfinamido)]pent-4-eneamide 
• 1287731-54-7 (2S,3R)-(+)-methyl 2-methyl-3-[(S)-(4-methylphenylsulfinamido)]-3-pent-4-enonate 
• 667457-55-8 (R)-(-)-N-(p-toluenesulfonyl)-6-amino-4-oxo-octa-2,7-diene 
• 667457-62-7 (S_S,4R,6R)-(+)-N-(p-toluenesulfinyl)-6-aminoocta-2,7-dien-4-ol 
• 667457-53-6 (S_S,R)-(+)-N-(p-toluenesulfinyl)-6-amino-4-oxo-octa-2,7-diene 

Relevant academic research and scientific papers

Asymmetric synthesis of the carbocyclic nucleoside building block (R)-(+)-4-aminocyclopentenone using δ-amino β-ketophosphonates and ring-closing metathesis (RCM)

Amino keto-2,7-dienes undergo ring-closing metathesis (RCM) to give 4-aminocyclopentenones, valuable intermediates in the asymmetric construction of carbocyclic nucleosides. The key amino ketodienes were prepared using δ-amino β-ketophophonates, a new sul