phenyl(p-carboran-2-yl)iodonium tetrafluoroborate

Base Information

Chemical Name:phenyl(p-carboran-2-yl)iodonium tetrafluoroborate
CAS No.:88242-78-8
Molecular Formula:BF₄*C₈H₁₆B₁₀I
Molecular Weight:434.034
Hs Code.:

Synonyms:phenyl(p-carboran-2-yl)iodonium tetrafluoroborate

Suppliers and Price of phenyl(p-carboran-2-yl)iodonium tetrafluoroborate

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

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Total 2 raw suppliers

Chemical Property of phenyl(p-carboran-2-yl)iodonium tetrafluoroborate

Chemical Property:

Purity/Quality:: 99% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Technology Process of phenyl(p-carboran-2-yl)iodonium tetrafluoroborate

There total 1 articles about phenyl(p-carboran-2-yl)iodonium tetrafluoroborate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 80.0%

: tetrafluoroboric acid

: 22784-33-4
2-iodo-closo-1,12-dodecaborane

: 88242-78-8
phenyl(p-carboran-2-yl)iodonium tetrafluoroborate

Guidance literature:: With dipotassium peroxodisulfate; benzene; In sulfuric acid; acetic anhydride; K2S2O( added at -12°C to a mixture of acetic anhydride, benzene,conc. H2SO4 and the B-compound, stirred for 1 h at 0-5°C and 7 hat 20°C, poured into ice; worked up as in: V. V. Grushuin, T. P. Tolstaya, and I. N. Lisichkina, Dokl. Akad. Nauk SSSR, 216, 99 (1981); CH2Cl2 soln. passed through an Al2O3 bed; elem. anal.;
DOI:10.1007/BF00954687

Reference yield: 99.5%

: 88242-78-8
phenyl(p-carboran-2-yl)iodonium tetrafluoroborate

: 7681-49-4
sodium fluoride

: 591-50-4
iodobenzene

: 22762-43-2
2-fluoro-p-caborane

: 932-72-9
(Dichloroiodo)benzene

Guidance literature:: With sodium fluoride; In dichloromethane; water; mixt. of iodonium salt, NaF, H2O and CH2Cl2 stirred at 25°C for 35 min; org. phase sepd. off, filtered through a short alumina plug and evapd., the residue is a mixt. of C6H5I and 2-fluoro-p-carborane; solid dissolved in dry CCl4; soln. satd. with Cl2 at 5°C, and then evapd., to give the mixt. of C6H3Cl2I and the fluorocarborane; the latter extd. with pentane, filtered through an alumina plug, evapd. to dryness, vac. sublimation; elem. anal.;