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Usage

Uses

Used in Organic Synthesis:
(Dichloroiodo)-benzene is used as a reagent in organic synthesis for its ability to facilitate the oxidation of alcohols and olefins. Its properties allow for the conversion of these substrates into more complex organic compounds, which are essential in the creation of pharmaceuticals, agrochemicals, and other specialty chemicals.
Used in Electrophilic Aromatic Substitution:
As a mild electrophile, (dichloroiodo)-benzene is utilized in electrophilic aromatic substitution reactions. This application is crucial for the synthesis of a variety of aromatic compounds, which have widespread uses in the chemical industry, including the production of dyes, plastics, and pharmaceuticals.
Used in Catalyst Development:
(Dichloroiodo)-benzene has been investigated for its potential as a catalyst in organic reactions. Its use in this capacity could enhance the efficiency and selectivity of various chemical processes, leading to more sustainable and cost-effective synthetic routes for the production of valuable chemical products.
Used in Research and Development:
In the field of chemical research, (dichloroiodo)-benzene serves as a valuable compound for studying reaction mechanisms and exploring new synthetic methodologies. Its unique reactivity and properties make it an interesting subject for academic and industrial research, potentially leading to the discovery of novel applications and improvements in existing chemical processes.

InChI:InChI=1/C6H5Cl2I/c7-9(8)6-4-2-1-3-5-6/h1-5H

Upstream product

• 536-80-1 iodosylbenzene 
• 3240-34-4 [bis(acetoxy)iodo]benzene 
• 106266-43-7 N-phenyliodonio α-phenylacetamide tosylate 
• 591-50-4 iodobenzene 
• 7782-50-5 chlorine 
• 7647-01-0 hydrogenchloride 
• 56-23-5 tetrachloromethane 
• 75-52-5 nitromethane 
• 7790-99-0 Iodine monochloride 
• 64-19-7 acetic acid 
• 507-20-0 tertiary butyl chloride 
• 2712-78-9 bis-[(trifluoroacetoxy)iodo]benzene 
• 10026-13-8 phosphorus pentachloride 
• 615-41-8 2-iodochlorobenzene 

Downstream Products

• 591-50-4 iodobenzene 
• 34557-54-5 methane 
• 74-84-0 ethane 
• 100-41-4 ethylbenzene 
• 5457-60-3 4-chloro-2,4,6-tri-tert-butylcyclohexa-2,5-dienone 
• 50869-79-9 N,N',N''-trimethyl-N,N',N''-triphenyl-phosphamide 
• 55954-20-6 1-(2-chloro-4,5-dimethoxy-benzyl)-6,7-dimethoxy-2-methyl-1,2,3,4-tetrahydro-isoquinoline 
• 5422-85-5 21-acetoxy-4ξ-chloro-17-hydroxy-5β-pregnane-3,11,20-trione 
• 628-76-2 1,5-dichloropentane 
• 287-92-3 Cyclopentane 
• 75-00-3 chloroethane 
• 107-27-7 ethylmercury(II) chloride 
• 92-52-4 biphenyl 
• 10182-84-0 diphenyliodonium 

Relevant academic research and scientific papers

Convenient chlorination with concentrated hydrochloric acid in the presence of iodosylbenzene

An efficient chlorination of -keto esters, 1,3-diketones, and alkenes was performed conveniently with concentrated HCl in the presence of PhIO, selectively giving -chloro - keto esters, 2-chloro-1,3-diketones, and 1,2-dichloroalkanes, respectively. It was suggested that the chlorination took place with (dichloroiodo)benzene generated in situ. A selective anti-addition was observed in the chlorination of indene. Georg Thieme Verlag Stuttgart New York.

One-pot procedures for preparing (dichloroiodo)arenes from arenes and diiodine, with chromium(VI) oxide as the oxidant

Ten representative (dichloroiodo)arenes, ArICl2, were prepared from the corresponding arenes and diiodine in variable anhydrous mixtures, ArH/I2/CrO3/AcOH/Ac2O/conc. H 2SO4, followed by the

One-pot preparations of (dichloroiodo)arenes from some arenes

Arenes (ArH) were substituted with some transient I3+ species, generated in situ in appropriate, anhydrous I2/NaIO4 or NaIO3/AcOH/Ac2O/concd H2SO4 mixtures, to form soluble organ

N-Phenyliodonio Carboxamide Tosylates: Synthesis and Hydrolysis to Alkylammonium Tosylates

The synthesis of N-phenyliodonio carboxamide tosylates from carboxamides and benzene and their degradative hydrolysis in acetonitrile to alkylammonium tosylates are described.

Oxidative Displacement of Halogen from Alkyl Halides by Phenyliodine(III) Dicarboxylates

The reaction of alkyl iodides with aryliodine(III) dicarboxylates affords as the main product the ester derived through substitution of iodine by an acyloxy group; in some cases α-iodoalkyl esters are also formed along with other minor products.Certain reactive bromides and chlorides react along similar lines.The mechanism of these reactions is briefly discussed.