diphenyl(2-(trimethylstannyl)phenyl)phosphane oxide

Base Information

• Chemical Name: diphenyl(2-(trimethylstannyl)phenyl)phosphane oxide
• CAS No.: 97106-63-3
• Molecular Formula: C₂₁H₂₃OPSn
• Molecular Weight: 441.097
• Mol file: 97106-63-3.mol

Synonyms:diphenyl(2-(trimethylstannyl)phenyl)phosphane oxide

Chemical Property of diphenyl(2-(trimethylstannyl)phenyl)phosphane oxide

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
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MSDS Files:

Useful:

Technology Process of diphenyl(2-(trimethylstannyl)phenyl)phosphane oxide

There total 3 articles about diphenyl(2-(trimethylstannyl)phenyl)phosphane oxide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 80.0%

diphenyl(2-(trimethylstannyl)phenyl)phosphane (97106-61-1) → diphenyl(2-(trimethylstannyl)phenyl)phosphane oxide (97106-63-3)

Guidance literature:

With dihydrogen peroxide; In dichloromethane; water; at 0 ℃; for 3h;

DOI:10.1002/anie.201509329

Reference yield:

(trimethylstannyl)diphenylphosphine (1213-51-0) → diphenyl(2-(trimethylstannyl)phenyl)phosphane oxide (97106-63-3)

Guidance literature:

Multi-step reaction with 2 steps

1.1: TurboGrignard / diethyl ether; tetrahydrofuran / 0.5 h / -78 °C / Inert atmosphere; Schlenk technique

1.2: 2 h / -78 - 20 °C / Inert atmosphere; Schlenk technique

2.1: dihydrogen peroxide / dichloromethane; water / 3 h / 0 °C

With TurboGrignard; dihydrogen peroxide; In tetrahydrofuran; diethyl ether; dichloromethane; water;

DOI:10.1002/anie.201509329

Reference yield:

diphenylphosphane (829-85-6) → diphenyl(2-(trimethylstannyl)phenyl)phosphane oxide (97106-63-3)

Guidance literature:

Multi-step reaction with 3 steps

1.1: 3 h / 20 °C

2.1: TurboGrignard / diethyl ether; tetrahydrofuran / 0.5 h / -78 °C / Inert atmosphere; Schlenk technique

2.2: 2 h / -78 - 20 °C / Inert atmosphere; Schlenk technique

3.1: dihydrogen peroxide / dichloromethane; water / 3 h / 0 °C

With TurboGrignard; dihydrogen peroxide; In tetrahydrofuran; diethyl ether; dichloromethane; water;

DOI:10.1002/anie.201509329

upstream raw materials:

diphenyl(2-(trimethylstannyl)phenyl)phosphane

(trimethylstannyl)diphenylphosphine

diphenylphosphane

Downstream raw materials:

[1,1'-biphenyl]-2,2'-diylbis(diphenylphosphane oxide)