(2E,6Z)-(R)-4,12-Bis-(tert-butyl-diphenyl-silanyloxy)-dodeca-2,6-dienal

Base Information

Chemical Name:(2E,6Z)-(R)-4,12-Bis-(tert-butyl-diphenyl-silanyloxy)-dodeca-2,6-dienal
CAS No.:85593-70-0
Molecular Formula:C₄₄H₅₆O₃Si₂
Molecular Weight:689.098
Hs Code.:

Synonyms:(2E,6Z)-(R)-4,12-Bis-(tert-butyl-diphenyl-silanyloxy)-dodeca-2,6-dienal

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of (2E,6Z)-(R)-4,12-Bis-(tert-butyl-diphenyl-silanyloxy)-dodeca-2,6-dienal

Chemical Property:

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Technology Process of (2E,6Z)-(R)-4,12-Bis-(tert-butyl-diphenyl-silanyloxy)-dodeca-2,6-dienal

There total 8 articles about (2E,6Z)-(R)-4,12-Bis-(tert-butyl-diphenyl-silanyloxy)-dodeca-2,6-dienal which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 80.0%

: 85593-69-7
(2E,6Z)-(R)-4-(tert-Butyl-diphenyl-silanyloxy)-12-hydroxy-dodeca-2,6-dienal

: 58479-61-1
tert-butylchlorodiphenylsilane

: 85593-70-0
(2E,6Z)-(R)-4,12-Bis-(tert-butyl-diphenyl-silanyloxy)-dodeca-2,6-dienal

Guidance literature:: With dmap; triethylamine; In dichloromethane;
DOI:10.1016/S0040-4039(00)85704-4

Reference yield:

: 53036-80-9
6-carboxy hexylidene triphenylphosphorane

: 85593-70-0
(2E,6Z)-(R)-4,12-Bis-(tert-butyl-diphenyl-silanyloxy)-dodeca-2,6-dienal

Guidance literature:: Multi-step reaction with 6 steps

1: 60 percent / tetrahydrofuran; hexamethylphosphoric acid triamide / -78 °C

2: 80 percent / LiAlH₄ / tetrahydrofuran / Heating

3: TFA / tetrahydrofuran; H₂O / 16 h / Ambient temperature

5: 50 percent / benzene / 6 h / 80 °C

6: 80 percent / DMAP, Et₃N / CH₂Cl₂

With dmap; lithium aluminium tetrahydride; triethylamine; trifluoroacetic acid; In tetrahydrofuran; N,N,N,N,N,N-hexamethylphosphoric triamide; dichloromethane; water; benzene;
DOI:10.1016/S0040-4039(00)85704-4

Reference yield:

: 85593-68-6
(Z)-(R)-2-(tert-Butyl-diphenyl-silanyloxy)-10-hydroxy-dec-4-enal

: 85593-70-0
(2E,6Z)-(R)-4,12-Bis-(tert-butyl-diphenyl-silanyloxy)-dodeca-2,6-dienal

Guidance literature:: Multi-step reaction with 2 steps

1: 50 percent / benzene / 6 h / 80 °C

2: 80 percent / DMAP, Et₃N / CH₂Cl₂

With dmap; triethylamine; In dichloromethane; benzene;
DOI:10.1016/S0040-4039(00)85704-4