1,1'-di(4-formylphenyl)-3,3',4,4'-tetramethylferrocene

Base Information

Chemical Name:1,1'-di(4-formylphenyl)-3,3',4,4'-tetramethylferrocene
CAS No.:1019638-06-2
Molecular Formula:C₂₈H₂₆FeO₂
Molecular Weight:450.36
Hs Code.:

Synonyms:1,1'-di(4-formylphenyl)-3,3',4,4'-tetramethylferrocene

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Chemical Property of 1,1'-di(4-formylphenyl)-3,3',4,4'-tetramethylferrocene

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Technology Process of 1,1'-di(4-formylphenyl)-3,3',4,4'-tetramethylferrocene

There total 1 articles about 1,1'-di(4-formylphenyl)-3,3',4,4'-tetramethylferrocene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 76.0%

: 2591-86-8
N-Formylpiperidine

: 1019638-04-0
1,1'-di(4-bromophenyl)-3,3',4,4'-tetramethylferrocene

: 1019638-06-2
1,1'-di(4-formylphenyl)-3,3',4,4'-tetramethylferrocene

Guidance literature:: With n-butyllithium; N,N,N,N,-tetramethylethylenediamine; In diethyl ether; (Ar); addn. of TMEDA to soln. of 1,1'-di(4-bromophenyl)-3,3',4,4'-tetramethylferrocene in Et2O at 0°C; addn. of n-BuLi; warming to room temp., stirring at this temp. for 1 d; addn. of N-formylpiperidine; stirring for 12 h; addn. dropwise ice-cooled 2 N HCl; sepn. of layers; extn. with CH2Cl2; drying of combined org. solns.; drying over MgSO4; filtration, evapn., chromy. (silica, cyclohexane/ethylacetate = 2:1);
DOI:10.1021/om701277p

Reference yield: 95.0%

: 1019638-06-2
1,1'-di(4-formylphenyl)-3,3',4,4'-tetramethylferrocene

: 1019638-08-4
1,1'-di(4-vinylphenyl)-3,3',4,4'-tetramethylferrocene

Guidance literature:: With n-butyllithium; In tetrahydrofuran; addn. of n-C4H9Li in THF to suspn. of (Ph3PCH3)I in THF at 0°C; addn. of 1,1'-di(4-formylphenyl)-3,3',4,4'-tetramethylferrocene in THF; warming to room temp.; stirring for 1 d; removal of volatiles on vac., chromy. (silica, cyclohexane/THF = 10/1);
DOI:10.1021/om701277p