[Ru(1,10-phenanthroline)(1,4,7-trithiacyclononane)(CCC₆H₄OMe-4)]PF₆

Base Information

• Chemical Name: [Ru(1,10-phenanthroline)(1,4,7-trithiacyclononane)(CCC₆H₄OMe-4)]PF₆
• CAS No.: 1190945-94-8
• Molecular Formula: C₂₇H₂₇N₂ORuS₃*F₆P
• Molecular Weight: 737.756
• Mol file: 1190945-94-8.mol

Synonyms:[Ru(1,10-phenanthroline)(1,4,7-trithiacyclononane)(CCC₆H₄OMe-4)]PF₆

Chemical Property of [Ru(1,10-phenanthroline)(1,4,7-trithiacyclononane)(CCC₆H₄OMe-4)]PF₆

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

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Technology Process of [Ru(1,10-phenanthroline)(1,4,7-trithiacyclononane)(CCC₆H₄OMe-4)]PF₆

There total 1 articles about [Ru(1,10-phenanthroline)(1,4,7-trithiacyclononane)(CCC₆H₄OMe-4)]PF₆ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 88.0%

ammonium hexafluorophosphate + [(1,4,7-trithiacyclononane)(1,10-phenanthroline)RuCl](PF6) (1159339-26-0) + 4-methoxyphenylacetylen (768-60-5) → [Ru(1,10-phenanthroline)(1,4,7-trithiacyclononane)(CCC6H4OMe-4)]PF6 (1190945-94-8)

Guidance literature:

With potassium hydroxide; In methanol; (Ar); using Schlenk techniques; addn. of excess HCCC6H4OMe to methanolicsoln. of ((1,4,7-trithiacyclononane)(phen)RuCl)(PF6) and KOH; reflux fo r 12 h; cooling; pptn., addn. of satd. methanolic soln. of NH4PF6; washing of ppt. with Et2O; drying under vac., recrystn. by slow diffusion of Et2O into MeCN or acetone; elem. anal.;

DOI:10.1021/om900511t

upstream raw materials:

[(1,4,7-trithiacyclononane)(1,10-phenanthroline)RuCl](PF₆)

4-methoxyphenylacetylen