W(CHC₂H₅){NC₆H₃(C₃H₇)2}{OCCH₃(CF₃)2}2

Base Information

• Chemical Name: W(CHC₂H₅){NC₆H₃(C₃H₇)2}{OCCH₃(CF₃)2}2
• CAS No.: 101249-42-7
• Molecular Formula: C₂₃H₂₉F₁₂NO₂W
• Molecular Weight: 763.32
• Mol file: 101249-42-7.mol

Synonyms:W(CHC₂H₅){NC₆H₃(C₃H₇)2}{OCCH₃(CF₃)2}2

Chemical Property of W(CHC₂H₅){NC₆H₃(C₃H₇)2}{OCCH₃(CF₃)2}2

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of W(CHC₂H₅){NC₆H₃(C₃H₇)2}{OCCH₃(CF₃)2}2

There total 4 articles about W(CHC₂H₅){NC₆H₃(C₃H₇)2}{OCCH₃(CF₃)2}2 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

W(CH-t-Bu)(N-2,6-diisopropylphenyl)(hexafluoro-tert-butoxide)2 (101249-40-5) + (Z)-pent-2-ene (627-20-3) → (Z)-2-Butene (590-18-1) + W(CHC2H5){NC6H3(C3H7)2}{OCCH3(CF3)2}2 (101249-42-7) + trans-2-Butene (624-64-6) + trans-3-Hexene (13269-52-8)

Guidance literature:

In not given; excess cis-2-pentene;;

DOI:10.1021/ja00270a056

Reference yield:

N-trimethylsilyl-2,6-diisopropylaniline (78923-65-6) → W(CHC2H5){NC6H3(C3H7)2}{OCCH3(CF3)2}2 (101249-42-7)

Guidance literature:

Multi-step reaction with 2 steps

1: NEt₃ / diethyl ether

2: not given

With NEt₃; In diethyl ether;

DOI:10.1021/ja00270a056

Reference yield:

W(C5H10){NC6H3(C3H7)2}{OCCH3(CF3)2}2 → W(CHC2H5){NC6H3(C3H7)2}{OCCH3(CF3)2}2 (101249-42-7) + W{CH(C2H5)CH(C2H5)CH(C2H5)}{NC6H3(C3H7)2}{OCCH3(CF3)2}2

Guidance literature:

With cis-3-hexene; In pentane; treating W(CHCMe3)(NAr){OCMe(CF3)2} with cis-3-hexene in pentane at -40°C , warming to 25°C, solvent removal after 15 min in vacuo, extn., cooling to -40°C, addn. of cis-3-hexene, pptn.; identification by (1)HNMR; ratio tungstacycle:W(CHEt)(NAr)(OCMe(CF3)2)2=80:20; isolation of the latter by repeated concg. etheric soln. of the mixt.;

DOI:10.1021/ja00213a014

upstream raw materials:

W(CH-t-Bu)(N-2,6-diisopropylphenyl)(hexafluoro-tert-butoxide)2

(Z)-pent-2-ene

cis-3-hexene

N-trimethylsilyl-2,6-diisopropylaniline

Downstream raw materials:

W(CHEt)(N-2,6-C₆H₃-i-Pr₂){OCMe(CF₃)2}2