W(CH-t-Bu)(N-2,6-diisopropylphenyl)(hexafluoro-tert-butoxide)2

Base Information

• Chemical Name: W(CH-t-Bu)(N-2,6-diisopropylphenyl)(hexafluoro-tert-butoxide)2
• CAS No.: 101249-40-5
• Molecular Formula: C₂₅H₃₃F₁₂NO₂W
• Molecular Weight: 791.373
• Mol file: 101249-40-5.mol

Synonyms:W(CH-t-Bu)(N-2,6-diisopropylphenyl)(hexafluoro-tert-butoxide)2

Chemical Property of W(CH-t-Bu)(N-2,6-diisopropylphenyl)(hexafluoro-tert-butoxide)2

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of W(CH-t-Bu)(N-2,6-diisopropylphenyl)(hexafluoro-tert-butoxide)2

There total 1 articles about W(CH-t-Bu)(N-2,6-diisopropylphenyl)(hexafluoro-tert-butoxide)2 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

W(=CHtBu)(=N-2,6-iPr2C6H3)Cl2(dme) + 1,1,1,3,3,3-hexafluoro-2-methylpropan-2-ol (1515-14-6) → W(CH-t-Bu)(N-2,6-diisopropylphenyl)(hexafluoro-tert-butoxide)2 (101249-40-5)

Guidance literature:

With triethylamine; In diethyl ether; at -30 - 20 ℃; for 3h;

Reference yield: 50.0%

(vinyl)trimethoxylsilane (2768-02-7) + W(CH-t-Bu)(N-2,6-diisopropylphenyl)(hexafluoro-tert-butoxide)2 (101249-40-5) → W{CHSi(OMe)3}(N-2,6-C6H3-i-Pr2){OCMe(CF3)2}2 (128971-38-0)

Guidance literature:

In pentane; byproducts: tert-butylethylene; N2-atmosphere; stirring (25°C, 30 min); evapn. (vac.), recrystn. (pentane, -40°C); elem. anal.;

DOI:10.1021/om00158a025

Reference yield:

W(CH-t-Bu)(N-2,6-diisopropylphenyl)(hexafluoro-tert-butoxide)2 (101249-40-5) + (Z)-pent-2-ene (627-20-3) → (Z)-2-Butene (590-18-1) + W(CHC2H5){NC6H3(C3H7)2}{OCCH3(CF3)2}2 (101249-42-7) + trans-2-Butene (624-64-6) + trans-3-Hexene (13269-52-8)

Guidance literature:

In not given; excess cis-2-pentene;;

DOI:10.1021/ja00270a056

upstream raw materials:

1,1,1,3,3,3-hexafluoro-2-methylpropan-2-ol

Downstream raw materials:

(Z)-2-Butene

W(CHC₂H₅){NC₆H₃(C₃H₇)2}{OCCH₃(CF₃)2}2

trans-2-Butene

trans-3-Hexene