(benzyl triphenylstannanedithiocarboxylate)pentacarbonyltungsten

Base Information

• Chemical Name: (benzyl triphenylstannanedithiocarboxylate)pentacarbonyltungsten
• CAS No.: 107557-53-9
• Molecular Formula: C₃₁H₂₂O₅S₂SnW
• Molecular Weight: 841.205
• Mol file: 107557-53-9.mol

Synonyms:(benzyl triphenylstannanedithiocarboxylate)pentacarbonyltungsten

Chemical Property of (benzyl triphenylstannanedithiocarboxylate)pentacarbonyltungsten

Chemical Property:

Purity/Quality:

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MSDS Files:

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Technology Process of (benzyl triphenylstannanedithiocarboxylate)pentacarbonyltungsten

There total 2 articles about (benzyl triphenylstannanedithiocarboxylate)pentacarbonyltungsten which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 48.0%

tungsten hexacarbonyl (14040-11-0) + benzyl triphenylstannanedithiocarboxylate (87451-07-8) → (benzyl triphenylstannanedithiocarboxylate)pentacarbonyltungsten (107557-53-9)

Guidance literature:

With C₄H₈O; In tetrahydrofuran; reaction of the ester with the activated metalcarbonyle in THF under Ar; evapn. of the solvent, chromy. on silicagel (THF/petroleum ether), recrystn. (n-hexane), elem. anal.;

Reference yield: 48.0%

tungsten pentacarbonyl tetrahydrofuran (36477-75-5) + benzyl triphenylstannanedithiocarboxylate (87451-07-8) → (benzyl triphenylstannanedithiocarboxylate)pentacarbonyltungsten (107557-53-9)

Guidance literature:

In tetrahydrofuran; soln. of W complex and Sn compound in THF was stirred under exclusion of light for 2 h;; reduced in vol., recrystd. from n-hexane;;

DOI:10.1016/S0020-1693(00)84371-6

Reference yield:

(benzyl triphenylstannanedithiocarboxylate)pentacarbonyltungsten (107557-53-9) → bis(triphenyltin) sulfide (77-80-5)

Guidance literature:

In not given; decompn. in soln.;

upstream raw materials:

tungsten hexacarbonyl

benzyl triphenylstannanedithiocarboxylate

tungsten pentacarbonyl tetrahydrofuran

Downstream raw materials:

bis(triphenyltin) sulfide