77-80-5

Usage

Chemical Properties

Colorless crystals. Sol in org solvs.

Hazard

Moderately toxic by ingestion.

InChI:InChI=1/6C6H5.S.2Sn/c6*1-2-4-6-5-3-1;;;/h6*1-5H;;;/rC36H30SSn2/c1-7-19-31(20-8-1)38(32-21-9-2-10-22-32,33-23-11-3-12-24-33)37-39(34-25-13-4-14-26-34,35-27-15-5-16-28-35)36-29-17-6-18-30-36/h1-30H

Upstream product

• 1256-06-0 (2S,5R,6R)-benzyl-3,3-dimethyl-7-oxo-6-(2-phenoxyacetamido)-4-thia-1-azabicyclo[3.2.0]heptane-2-carboxylate 
• 892-20-6 triphenylstannane 
• 75-15-0 carbon disulfide 
• 870-23-5 prop-2-ene-1-thiol 
• 5285-87-0 phenyl thiocyanate 
• 100-53-8 phenylmethanethiol 
• 538-74-9 dibenzyl sulfide 
• 1450-31-3 Thiobenzophenon 
• 1064-10-4 hexaphenylditin 
• 52-90-4 L-Cysteine 
• 1262-21-1 bis(triphenyltin) oxide 
• 75-66-1 2-methylpropan-2-thiol 
• 7783-06-4 hydrogen sulfide 
• 639-58-7 triphenyltin chloride 

Downstream Products

• 111-31-9 Hexanethiol 
• 3910-39-2 tris(pentafluorophenyl)antimony 
• 639-58-7 triphenyltin chloride 
• 117012-58-5 (C₆H₅)3SnSSn(C₆H₁₁)3 
• 894-09-7 iodotriphenylstannane 
• 7704-34-9 sulfur 
• 595-90-4 tetraphenyltin(IV) 
• 117012-57-4 (C₄H₉)3SnSSn(C₆H₅)3 
• 117012-54-1 (C₄H₉)3SnOSn(C₆H₅)3 
• 4808-30-4 bis(tributyltin)sulfide 
• 1262-21-1 bis(triphenyltin) oxide 
• 17145-47-0 (C₆H₅)3SnC(N₂)COOC₂H₅ 
• 17145-49-2 (C₆H₅)3SnC(CO₂C₂H₅)CH₂C(CH₃)2 
• 21247-35-8 diphenyl methyl tin bromide 

Relevant academic research and scientific papers

HEXAORGANO-SUBSTITUTED TRIATOMICS R3XYZR3: THE CONFIGURATIONS OF ORGANOMETALLIC SULPHIDES (R3M)2S AND THE CRYSTAL AND MOLECULAR STRUCTURE OF THIO-BIS

Crystals of thio-bis, S(Ph3Sn)2, are orthorhombic, space-group P212121, with a = 18.469(5), b = 17.648(5), c = 9.848(6) Angstroem and Z = 4.The SnS distances are 2.405(9) and 2.417(7) Angstroem and SnSSn angle is 107.3(2) deg: there are no anomalous features in the structure analogous to those in O(Ph3Sn)2.MNDO calculations for a series of organometallic sulphides +n (M = Be, B, C, N, Si, P) indicate that the inversion barrier to linearity increases monotonically, and the skeletal bending force constant at linearity decreases correspondingly as the group Me3M becomes more electronegative.

Structural studies on Ph3MSMPh3 (M = Sn, Pb): Quest for a metal-metal bond

The title compounds Ph3PbSPbPh3 (1) and Ph3SnSSnPh3 (2) were prepared in high yields by a reaction of Na2S, respectively, with Ph3Pb(SOCMe) and Ph3Sn(SOCMe). X-ray crystallograph

19F NMR studies of the comparative electronegativity of the Ph3E groups (E = C, Si, Ge, Sn, or Pb) in Ph3E derivatives of tris(4-fluorophenyl)stannanethiol

Compounds (4-FC6H4)3SnSEPh3 (E = C, Si, Ge, Sn, or Pb) were synthesized or generated in solution. The data on the comparative electronegativity of the Ph3E groups were obtained from the results of su

DESULPHURISATION OF PENICILLINS WITH TRIPHENYLSTANNANE

Reaction of penicillins (and a cephalosporin) with triphenylstannane provide a novel and efficient route to dethioazetidinones.A study on the mechanism of this process is described.

Nucleophilic Addition of Triorganotin Anions to Carbon Disulfide, IX. - Synthesis and Complexation of Novel Triphenylstannane Dithioesters

The known alkyl esters Ph3SnC(S)SR (1: R = Me, 2: R = CH2Ph) and the novel stannyl(methyl) esters (3: R = SnPh3, 4: R = CH2SnPh3) were obtained by the reaction of the dioxane adduct Ph3SnCS2Li*2C4H8O2 with appropriate organo(element) halides.As the first derivative of a homologous stannylalkanedithiocarboxylic acid, the 3-(triphenylstannyl)propane dithioester Ph3SnC(S)SMe (5) was synthesized by Grignard reaction of (3-chloropropyl)triphenylstannane with activated magnesium (addition of anthracene, ultrasound).The new η1-coordinated pentacarbonylchromium and -tungsten complexes LM(CO)5 (1a: L = 1, M = Cr; 2a: L = 2, M = Cr; 2b: L = 2, M = W; 3b: L = 3, M = W; 5b: L = 5, M = W) were prepared by modification of previously reported methods.